Hydrogen in Palladium and Storage Properties of Related Nanomaterials: Size, Shape, Alloying, and Metal‐Organic Framework Coating Effects

Dekura Shun; Kobayashi Hirokazu; Kusada Kohei; Kitagawa Hiroshi

摘要

Abstract >One of the key issues for an upcoming hydrogen energy‐based society is to develop highly efficient hydrogen‐storage materials. Among the many hydrogen‐storage materials reported, transition‐metal hydrides can reversibly absorb and desorb hydrogen, and have thus attracted much interest from fundamental science to applications. In particular, the Pd?H system is a simple and classical metal‐hydrogen system, providing a platform suitable for a thorough understanding of ways of controlling the hydrogen‐storage properties of materials. By contrast, metal nanoparticles have been recently studied for hydrogen storage because of their unique properties and the degrees of freedom which cannot be observed in bulk, i.?e., the size, shape, alloying, and surface coating. In this review, we overview the effects of such degrees of freedom on the hydrogen‐storage properties of Pd‐related nanomaterials, based on the fundamental science of bulk Pd?H. We shall show that sufficiently understanding the nature of the interaction between hydrogen and host materials enables us to control the hydrogen‐storage properties though the electronic‐structure control of materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >即将到来的氢能社会的关键问题之一是开发高效的氢-Stage材料。在报告的许多氢储存材料中，过渡金属氢化物可以可逆地吸收和解吸氢，因此吸引了对应用的基本科学的兴趣。特别地，PDαH系统是一种简单且经典的金属氢系统，提供适合于彻底理解控制材料氢储存性能的方式的平台。相比之下，最近已经研究了金属纳米颗粒，因为它们具有独特的性质和不能在散装中不能观察到的自由度，即，尺寸，形状，合金化和表面涂层。在这篇综述中，我们概述了基于散装PD的基本科学的PD相关纳米材料氢储存性能的效果。我们将表明，充分了解氢气和主体材料之间的相互作用的性质使我们能够控制储氢性能，尽管材料的电子结构控制。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第10期</span><b style="margin: 0 2px;">|</b><span>共19页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dekura Shun&option=202" target="_blank" rel="nofollow">Dekura Shun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kobayashi Hirokazu&option=202" target="_blank" rel="nofollow">Kobayashi Hirokazu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kusada Kohei&option=202" target="_blank" rel="nofollow">Kusada Kohei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kitagawa Hiroshi&option=202" target="_blank" rel="nofollow">Kitagawa Hiroshi;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Division of Chemistry Graduate School of ScienceKyoto University Kitashirakawa-Oiwakecho Sakyo-kuKyoto 606-8502 Japan;</p> <p>Division of Chemistry Graduate School of ScienceKyoto University Kitashirakawa-Oiwakecho Sakyo-kuKyoto 606-8502 Japan;</p> <p>Division of Chemistry Graduate School of ScienceKyoto University Kitashirakawa-Oiwakecho Sakyo-kuKyoto 606-8502 Japan;</p> <p>Division of Chemistry Graduate School of ScienceKyoto University Kitashirakawa-Oiwakecho Sakyo-kuKyoto 606-8502 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hybrid materials&option=203" rel="nofollow">hybrid materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydrogen storage&option=203" rel="nofollow">hydrogen storage;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoparticles&option=203" rel="nofollow">nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=palladium&option=203" rel="nofollow">palladium;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid-solution alloys&option=203" rel="nofollow">solid-solution alloys;</a> </p> <div class="translation"> 机译：混合材料;储氢;纳米粒子;钯;固溶合金; 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rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王媛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘德晔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘德晔</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吉文亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吉文亮</a> <span> <a href="/journal-cn-6547/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 华中科技大学学报（医学版） </a> </span> <span> . 2020</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201275748705.html">一种二氯四氨合钯(Ⅱ)镀钯试剂的生产工艺及应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄世盛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 黄世盛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢卓森&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谢卓森</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2019</span><span>,第020期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-inorganic-chemistry_thesis/0201250739537.html">四氯合钯(Ⅱ)酸双{4-溴-2,6-二(N,N-二乙基氨基亚甲基)吡啶基氯化钯(Ⅱ)}的合成及晶体结构</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高宏飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高宏飞</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱敦如&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱敦如</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨刚</a> <span> <a href="/journal-cn-15070/" target="_blank" rel="nofollow" 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