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首页> 外文期刊>Chemphyschem: A European journal of chemical physics and physical chemistry >Quantum Chemical Analyses of BH 44 ?? and BH 33 OH ?? Hydride Transfers to CO 22 in Aqueous Solution with Potentials of Mean Force
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Quantum Chemical Analyses of BH 44 ?? and BH 33 OH ?? Hydride Transfers to CO 22 in Aqueous Solution with Potentials of Mean Force

机译：BH 4 4 的量子化学分析？？ 和Bh 3 3 oh ？？ 氢化物转移到水溶液中的Co 2 2，其具有平均力的潜力

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Abstract > Biomimetic hydride transfer catalysts are a promising route to efficiently convert CO <sub>2</sub> into more useful products, but a lack of understanding about their atomic‐scale reaction mechanisms slows their development. To this end, we report a computational quantum chemistry study of how aqueous solvation influences CO <sub>2</sub> reduction reactions facilitated by sodium borohydride (NaBH <sub>4</sub> ) and a partially oxidized derivative (NaBH <sub>3</sub> OH). This work compares 0?K reaction barriers from nudged elastic band calculations to free‐energy barriers obtained at 300?K using potentials of mean force from umbrella sampling simulations. We show that explicitly treating free energies from reaction pathway sampling has anywhere from a small to a large effect on the reaction‐energy profiles for aqueous‐phase hydride transfers to CO <sub>2</sub> . Sampling along predefined reaction coordinates is thus recommended when it is computationally feasible. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“EN”> <标题类型=“main”>摘要</标题> >杀生物摩擦转移催化剂是有效转换CO <SUB> 2 </ sub的有希望的路线>进入更有用的产品，但对其原子规模反应机制缺乏了解，减缓了他们的发展。为此，我们报告了一种计算量子化学研究，这些研究对含水溶剂化的水性溶剂化程度的影响CO <sub> 2 - 酸钠（NABH <sub> 4 </ sub>）和部分氧化衍生物（NABH <）促进的还原反应Sub> 3 </ sub> OH）。这项工作将0·K反应屏障与闪烁的弹性带计算比较到300Ω·k的自由能屏障，使用来自伞采样模拟的平均力的电位。我们表明，从反应途径采样明确地处理来自反应途径采样的自由能量，对于水相氢化物转移到CO <sub> 2 </ sub>的反应 - 能量曲线具有很大效果。因此建议在计算可行时沿预定义反应坐标进行采样。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2017年第22期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Groenenboom Mitchell C.&option=202" target="_blank" rel="nofollow">Groenenboom Mitchell C.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Keith John A.&option=202" target="_blank" rel="nofollow">Keith John A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemical and Petroleum Engineering Swanson School of EngineeringUniversity of PittsburghPittsburgh PA 15213 USA;</p> <p>Department of Chemical and Petroleum Engineering Swanson School of EngineeringUniversity of PittsburghPittsburgh PA 15213 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon dioxide&option=203" rel="nofollow">carbon dioxide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=density functional theory&option=203" rel="nofollow">density functional theory;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hydride transfer&option=203" rel="nofollow">hydride transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molecular dynamics&option=203" rel="nofollow">molecular dynamics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=umbrella sampling&option=203" rel="nofollow">umbrella sampling;</a> </p> <div class="translation"> 机译：二氧化碳;密度函数理论;氢化物转移;分子动力学;伞采样; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022114766.html">Quantum Chemical Analyses of BH <sub >4</sub>4 <sup >?? and BH <sub >3</sub>3 OH <sup >?? Hydride Transfers to CO <sub >2</sub>2 in Aqueous Solution with Potentials of Mean Force</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Groenenboom Mitchell C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Groenenboom Mitchell C.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Keith John A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Keith John A. </a> <a href="/journal-foreign-16300/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chemphyschem: A European journal of chemical physics and physical chemistry .</a> <span>2017</span><span>,第22期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：BH <sub> 4 </ sub> 4 的量子化学分析？</ sup>？ 和Bh <sub> 3 </ sub> 3 oh ？</ sup>？ 氢化物转移到水溶液中的Co <sub> 2 </ sub> 2，其具有平均力的潜力</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022115908.html">Quantum Chemical Analyses of BH <sub >4</sub>4 <sup >?? and BH <sub >3</sub>3 OH <sup >?? 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href="/journal-cn-15102/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 物理化学学报 </a> </span> <span> . 2007</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-shanxi-normal-university-natural-science-edition_thesis/0201293410818.html">硼烷原子簇化合物的量子化学研究 Ⅰ.BH_3、B_2H_6和B_3H_9中化学成键性质的理论研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=武海顺&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 武海顺</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=潘道皚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,潘道皚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周伟良&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周伟良</a> <span> <a href="/journal-cn-53413/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 山西师范大学学报：自然科学版 </a> </span> <span> . 1991</span><span>,第1期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-materials-science-engineering_thesis/0201211535776.html">配位氢化物储氢材料Mg（BH4）2的研究进展</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈君儿&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈君儿</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=熊智涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,熊智涛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴国涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴国涛</a> <span> <a href="/journal-cn-7649/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 材料科学与工程学报 </a> </span> <span> . 2011</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-sichuan-university-natural-science-edition_thesis/0201250501724.html">用量子力学从头算方法计算BH基态分子(X1∑+)的结构与势能函数</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=岳莉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 岳莉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴位巍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴位巍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=令狐荣锋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,令狐荣锋</a> <span> <a href="/journal-cn-4696/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 四川大学学报（自然科学版） </a> </span> <span> . 2007</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-25117_thesis/020221311555.html">BHS构造勘探潜力分析</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=程耀清&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 程耀清</a> <span> <a href="/conference-cn-25117/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国石油学会东部地区第十三次物探技术研讨会 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312817810.html">三元金属氢化物Mg(BH4)2高压相变的第一性原理研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高铭蔚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高铭蔚</a> <span> . 2013</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120105269987.html">包含唯BH3域蛋白中BH3结构域的融合蛋白</a> <b>[P]</b> . <span> 中国专利： CN101068832A </span> <span> . 2007-11-07</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061203018313.html">机械力诱导合成γ-Ca(BH</a> <b>[P]</b> . <span> 中国专利： CN106315512B </span> <span> . 2018.09.11</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130487723312.html">REACTION PRODUCTS OF ALANE TERMINATED BERYLLIUM HYDRIDE WITH B2H6,BE(BH4)2 OR B4H10</a> <b>[P]</b> . <span> 外国专利： <!-- 美国专利： --> US3484315A </span> <span> . 1969-12-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：烷烃封端的铍与B2H6，BE（BH4）2或B4H10的反应产物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130436609892.html">Monolithic integrated BH-laser structure, has diffusion active laser layer exhibiting integrated tapering in lateral direction towards on front facet in formation of structure as reinforcement unit</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE202005015673U1 </span> <span> . 2005-12-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：单片集成BH激光器结构，具有扩散有源激光层，在结构形成中作为增强单元，扩散有源激光层在横向方向上朝前端面呈现集成锥形 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130448189893.html">Transferring material through cell membranes, useful e.g. in genetic engineering or hydride production, using aqueous solution containing trehalose, increases cell survival</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE10010959A1 </span> <span> . 2001-09-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过细胞膜转移物质，例如在基因工程或氢化物生产中，使用含有海藻糖的水溶液可提高细胞存活率 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" 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