Lithiation Behavior of Silicon Nanowire Anodes for Lithium‐Ion Batteries: Impact of Functionalization and Porosity

Schmerling Marcus; Fenske Daniela; Peters Fabian; Schwenzel Julian; Busse Matthias

摘要

Abstract > Metal‐assisted chemical etching (MACE) provides a versatile way to synthesize silicon nanowires (SiNW) of different morphologies. MACE was used to synthesize oxide‐free porous and nonporous SiNW for use as anodes for lithium‐ion batteries. To improve their processing behavior, the SiNW were functionalized using acrylic acid. Differential capacity plots were used as a way to identify the degradation processes during cycling through tracking the formation of Li <sub>15</sub> Si <sub>4</sub> and changes in polarization. The cycling performance between porous and nonporous SiNW differed regarding Coulombic efficiency and cycling stability. The differences were attributed to the porous hull and its ability to reduce the volume expansion, although not through its porous nature but the reduced uptake of Li?ions. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >金属辅助化学蚀刻（MACE）为合成硅纳米线（SINW）提供了一种多功能的方式不同的形态。佩纳用于合成无氧多孔和无孔SINW以用作锂离子电池的阳极。为了提高其加工行为，使用丙烯酸官能化SINW。用差分容量图作为识别循环过程中识别劣化过程的方法，通过跟踪Li <Sub> 15 </ sub> Si <sub> 4 </ sub>的形成以及极化的变化。多孔和无孔SINW之间的循环性能与库仑效率和循环稳定性不同。差异归因于多孔船体及其降低体积膨胀的能力，尽管不是通过其多孔性质，但李氏菌的摄取降低。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第1期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schmerling Marcus&option=202" target="_blank" rel="nofollow">Schmerling Marcus;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fenske Daniela&option=202" target="_blank" rel="nofollow">Fenske Daniela;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Peters Fabian&option=202" target="_blank" rel="nofollow">Peters Fabian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schwenzel Julian&option=202" target="_blank" rel="nofollow">Schwenzel Julian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Busse Matthias&option=202" target="_blank" rel="nofollow">Busse Matthias;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Electrical Energy Storage Fraunhofer IFAMWiener Stra?e 12 28359 Bremen Germany;</p> <p>Electrical Energy Storage Fraunhofer IFAMWiener Stra?e 12 28359 Bremen Germany;</p> <p>Electrical Energy Storage Fraunhofer IFAMWiener Stra?e 12 28359 Bremen Germany;</p> <p>Electrical Energy Storage Fraunhofer IFAMWiener Stra?e 12 28359 Bremen Germany;</p> <p>Electrical Energy Storage Fraunhofer IFAMWiener Stra?e 12 28359 Bremen Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=functionalization&option=203" rel="nofollow">functionalization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium-ion batteries&option=203" rel="nofollow">lithium-ion batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mesoporous materials&option=203" rel="nofollow">mesoporous materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal-assisted chemical etching&option=203" rel="nofollow">metal-assisted chemical etching;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silicon anodes&option=203" rel="nofollow">silicon anodes;</a> </p> <div class="translation"> 机译：功能化;锂离子电池;中孔材料;金属辅助化学蚀刻;硅阳极; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> 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WANG Deng-Jun</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王邓军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王邓军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=WANG Yan-Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,WANG Yan-Li</a> <span> <a href="/conference-cn-60758/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国金属学会炭素材料分会第三十二届学术交流会 </a> <span> <span> . 2018</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312571977.html">锂离子电池电极中扩散诱导位错及锂化行为的机理研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李向东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李向东</a> <span> . 2016</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204394184.html">锂离子电池负极预锂化的方法和经过预锂化的锂离子电池的制备方法</a> <b>[P]</b> . <span> 中国专利： CN111261836B </span> <span> . 2021.05.11</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103917542.html">锂离子电池负极预锂化的方法和经过预锂化的锂离子电池的制备方法</a> <b>[P]</b> . <span> 中国专利： CN111261836A </span> <span> . 2020-06-09</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130405890452.html">- Manufacturing method for anode active material of lithium secondary battery comprising carbon composite nano particle with silicon porosity anode active material of lithium secondary battery manufactured by the same and lithium secondary battery comprising the same</a> <b>[P]</b> . <span> 外国专利：  KR101875950B1 </span> <span> . 2018-07-12</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-包含碳复合纳米颗粒的锂二次电池负极活性物质的制造方法，该碳复合纳米粒子具有由其制造的锂二次电池的硅孔隙率负极活性物质和包括该复合材料的锂二次电池 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130419441731.html">MANUFACTURING METHOD FOR ANODE ACTIVE MATERIAL OF LITHIUM SECONDARY BATTERY COMPRISING CARBON COMPOSITE NANO PARTICLE WITH SILICON POROSITY, ANODE ACTIVE MATERIAL OF LITHIUM SECONDARY BATTERY MANUFACTURED BY THE SAME, AND LITHIUM SECONDARY BATTERY COMPRISING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR20130071070A </span> <span> . 2013-06-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含碳多孔性的碳纳米复合颗粒锂二次电池的正极活性物质的制造方法，相同方法制造的锂二次电池的阳极活性物质以及相同构成的锂二次电池的制造方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130407622238.html">Mass production method of silicon nanowire and / or nanobelt, and lithium battery and anode using silicon nanowire and / or nanobelt</a> <b>[P]</b> . <span> 外国专利：  JP6383412B2 </span> <span> . 2018-08-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硅纳米线和/或纳米带的批量生产方法以及使用硅纳米线和/或纳米带的锂电池和阳极 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022114537','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img 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