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首页> 外文期刊>Chemphyschem: A European journal of chemical physics and physical chemistry >Comparative Study of Molecular Basket Sorbents Consisting of Polyallylamine and Polyethylenimine Functionalized SBA‐15 for CO 22 Capture from Flue Gas
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Comparative Study of Molecular Basket Sorbents Consisting of Polyallylamine and Polyethylenimine Functionalized SBA‐15 for CO 22 Capture from Flue Gas

机译:由烟气中的CO 2 2捕获的聚烯丙胺和聚乙基官能化SBA-15组成的分子篮子吸附剂的比较研究

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摘要

Abstract > Polyallylamine (PAA)‐based molecular basket sorbents (MBS) have been studied for CO <sub>2</sub> capture in comparison with polyethylenimine (PEI)‐based MBS. The characterizations including N <sub>2</sub> physisorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and thermogravimetric analysis (TGA) showed that PAA ( M <sub>n</sub> =15?000) is more rigid and has more steric hindrance inside SBA‐15 pores than PEI owing mainly to its different polymer structure. The effects of temperature and PAA loading on the CO <sub>2</sub> sorption capacity of PAA‐based MBS have been examined by TGA by using 100?% CO <sub>2</sub> gas stream and compared with PEI/SBA‐15. It was found that the capacity of the PAA/SBA‐15 sorbent increased with increasing temperature. The optimum capacity of 88?mg <sub>CO2</sub> ?g <sub>sorb</sub> ?1 was obtained at 140?°C for PAA(50)/SBA‐15 whereas the optimum sorption temperature was 75 and 90?°C for PEI‐I(50)/SBA‐15 (PEI‐I, M <sub>n</sub> =423) and PEI‐II(50)/SBA‐15 (PEI‐II, M <sub>n</sub> =25?000), respectively. The capacity initially increased with the increase of PAA loading and then dropped at high amine contents, owing to the increased diffusion barrier. The highest CO <sub>2</sub> capacity of 109?mg <sub>CO2</sub> ?g <sub>sorb</sub> ?1 was obtained at a PAA loading of 65?wt?%, whereas the PAA(50)/SBA‐15 sorbent gave the best amine efficiency of 0.23?mol <sub>CO2</sub> ?mol <sub>N</sub> ?1 . The effect of moisture was examined in a fixed‐bed flow sy </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> >聚烯丙胺(PAA)基于CO <SUB的基于分子篮子吸附剂(MBS) > 2 </ sub>与聚乙烯亚胺(PEI)的MBS相比捕获。包括N <sub> 2 </ sub>理由,漫反射率红外傅里叶变换光谱(漂移)和热重分析(TGA)的表征显示PAA( m </ i> <sub> n </ sub> = 15?000)更加刚性并且在SBA-15孔内部具有比其不同的聚合物结构的PEI更空间的障碍。 TGA通过使用100μl%CO <sub> 2 </ sub>气流并与PEI相比,通过TGA研究了温度和PAA加载对基于PAA的MBS的CO 2 </ sub>吸附能力的影响。 / SBA-15。发现PAA / SBA-15吸附剂的容量随着温度的增加而增加。在140°C对于PAA(50)/ SBA-15,获得最佳容量为88Ωmg<sub> CO 2 </ sub>β1/ soSb α1-sup>而最佳吸附温度为PEI-1(50)/ SBA-15(PEI-I,<I> M </ I> <Sub> N </ Sub> = 423)和PEI- II(50)/ SBA-15(PEI-II,<I> M </ I> <亚> N </ SUB> = 25 000)。由于增加的扩散屏障,该容量最初随着PAA负荷的增加而增加,然后在高胺含量下掉落。在PAA负载下获得最高的Co <sub> Co 2 </ sub> CO 2的容量为109〜mg <sub> co2 </ sub> srob 1/po> 65?wt?%,而PAA(50)/ SBA-15吸附剂使最佳胺效率为0.23Ω·mol <sub> CO 2 </ sub> n </ sub> 1 < / sup>。在固定床流量系统中检查了水分的影响 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2017年第22期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Dongxiang&option=202" target="_blank" rel="nofollow">Wang Dongxiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiaoxing&option=202" target="_blank" rel="nofollow">Wang Xiaoxing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Chunshan&option=202" target="_blank" rel="nofollow">Song Chunshan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Clean Fuels and Catalysis ProgramPennsylvania State University209 Academic Projects Building University Park PA 16802 USA;</p> <p>Clean Fuels and Catalysis ProgramPennsylvania State University209 Academic Projects Building University Park PA 16802 USA;</p> <p>Clean Fuels and Catalysis ProgramPennsylvania State University209 Academic Projects Building University Park PA 16802 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学(理论化学)、化学物理学">物理化学(理论化学)、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=CO 2 capture&option=203" rel="nofollow">CO 2 capture;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molecular basket sorbent&option=203" rel="nofollow">molecular basket sorbent;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyallylamine&option=203" rel="nofollow">polyallylamine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyethylenimine&option=203" rel="nofollow">polyethylenimine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=SBA-15&option=203" rel="nofollow">SBA-15;</a> </p> <div class="translation"> 机译:二氧化碳捕获;分子篮子吸附剂;聚乙基亚胺;聚乙烯亚胺;SBA-15; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022115898.html">Cover Feature: Comparative Study of Molecular Basket Sorbents Consisting of Polyallylamine and Polyethylenimine Functionalized SBA‐15 for CO <sub >2</sub>2 Capture from Flue Gas (ChemPhysChem 22/2017)</a> <b>[J]</b> . <span> <a 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2008</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-43337_thesis/020222759938.html">基于聚二氧乙基噻吩/石墨烯构建高性能眼用生物传感器基于聚二氧乙基噻吩/石墨烯构建高性能眼用生物传感器</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=董贡献&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 董贡献</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张文晶&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张文晶</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘勇</a> <span> <a href="/conference-cn-43337/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2017中国生物材料大会 </a> <span> <span> . 2017</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" 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