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首页> 外文期刊>Chemphyschem: A European journal of chemical physics and physical chemistry >Modulation of Excited‐State Proton‐Transfer Dynamics inside the Nanocavity of Microheterogeneous Systems: Microenvironment‐Sensitive F?rster Energy Transfer to Riboflavin
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Modulation of Excited‐State Proton‐Transfer Dynamics inside the Nanocavity of Microheterogeneous Systems: Microenvironment‐Sensitive F?rster Energy Transfer to Riboflavin

机译:微源系统纳米恒温内的兴奋状态质子传递动力学的调制:微环境敏感F?罗斯特能量转移到核黄素

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Abstract >The excited‐state proton‐transfer efficiency of a tetraarylpyrene derivative, 1,3,6,8‐tetrakis(4‐hydroxy‐2,6‐dimethylphenyl)pyrene (TDMPP), was investigated thoroughly in the presence of various surfactant assemblies, such as micelles and vesicles. The confined microheterogeneous environments can significantly retard the extent of the excited‐state proton‐transfer process, resulting in a distinguishable optical signal compared to that in the bulk medium. Physical characteristics of the surfactant assemblies, such as order, interfacial hydration, and surface charge, influence the proton transfer process and allow multiparametric sensing. A higher degree of interfacial hydration facilitates the proton‐transfer process, while the positively charged head groups of the surfactants specifically stabilize the anionic form of the probe (TDMPP?O*). Furthermore, Forster energy transfer from the probe to riboflavin was studied in a phospholipid membrane, wherein the relative ratio of the neutral versus anionic forms (TDMPP‐OH/TDMPP?O*) was found to influence the extent of energy transfer. Overall, we demonstrate how an ultrafast photophysical process, that is, the excited‐state proton transfer, can be influenced by the microenvironment. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><abstract type =“main”xml:lang =“en”> <title type =“main”>抽象</ title> >四芳戊烯衍生物的激发态质子传递效率,1,3,6,在各种表面活性剂组件(例如胶束和囊泡)存在下彻底研究了8-四羟基-2,6-二甲基苯基)芘(TDMPP)。密闭的微雌性环境可以显着延迟激发态质子转移过程的程度,从而导致与散装介质中的可区分光学信号相比。表面活性剂组件的物理特性,例如订单,界面水合和表面电荷,影响质子转移过程并允许多射度传感。更高程度的界面水合促进了质子转移过程,而表面活性剂的带正电的头部基团特异性稳定探针的阴离子形式(TDMPPα0*)。此外,在磷脂膜中研究了从探针到核黄素的福尔斯特能量转移,其中发现中性与阴离子形式的相对比(TDMPP-OH /TDMPPβO*)影响能量转移的程度。总体而言,我们展示了如何通过微环境的影响,即励磁质子转移的超快光药过程。</ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第6期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dey Nilanjan&option=202" target="_blank" rel="nofollow">Dey Nilanjan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Biswakarma Dipen&option=202" target="_blank" rel="nofollow">Biswakarma Dipen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bajpai Alankriti&option=202" target="_blank" rel="nofollow">Bajpai Alankriti;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Moorthy Jarugu Narasimha&option=202" target="_blank" rel="nofollow">Moorthy Jarugu Narasimha;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bhattacharya Santanu&option=202" target="_blank" rel="nofollow">Bhattacharya Santanu;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Organic ChemistryIndian Institute of ScienceBangalore 560012 India;</p> <p>Department of Organic ChemistryIndian Institute of ScienceBangalore 560012 India;</p> <p>Department of ChemistryIndian Institute of Technology KalyanpurKanpur Uttar Pradesh 208016;</p> <p>Department of ChemistryIndian Institute of Technology KalyanpurKanpur Uttar Pradesh 208016;</p> <p>Department of Organic ChemistryIndian Institute of ScienceBangalore 560012 India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学(理论化学)、化学物理学">物理化学(理论化学)、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=energy transfer&option=203" rel="nofollow">energy transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=excited-state proton transfer&option=203" rel="nofollow">excited-state proton transfer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=microenvironment&option=203" rel="nofollow">microenvironment;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=microheterogeneous system&option=203" rel="nofollow">microheterogeneous system;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surfactants&option=203" rel="nofollow">surfactants;</a> </p> <div class="translation"> 机译:能量转移;兴奋状态质子转移;微环境;微观环境;表面活性剂; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022114449.html">Modulation of Excited‐State Proton‐Transfer Dynamics inside the Nanocavity of Microheterogeneous Systems: Microenvironment‐Sensitive F?rster Energy Transfer to Riboflavin</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dey Nilanjan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dey Nilanjan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Biswakarma Dipen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Biswakarma Dipen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bajpai Alankriti&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bajpai Alankriti,</a> <a href="/journal-foreign-16300/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chemphyschem: A European journal of chemical physics and physical chemistry .</a> <span>2019</span><span>,第6期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:微源系统纳米恒温内的兴奋状态质子传递动力学的调制:微环境敏感F?罗斯特能量转移到核黄素</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019206724.html">Excited State Proton Transfer Dynamics of Topotecan Inside Biomimicking Nanocavity</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Koninti Raj Kumar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Koninti Raj Kumar,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gavvala Krishna&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gavvala Krishna,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sengupta Abhigyan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sengupta Abhigyan,</a> <a href="/journal-foreign-30976/" target="_blank" rel="nofollow" class="tuijian_authcolor">The journal of physical chemistry, B. 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