Predicting glass-to-glass and liquid-to-liquid phase transitions in supercooled water using classical nucleation theory

摘要

Graphical abstractDisplay OmittedHighlights?A model of two phases 1 & 2 works to describe water thermodynamic properties.?The strong liquids 1 & 2 give rise to glass Phase 3 below various Tg.?First-order transitions under pressure leads to high-density Phase 3 at Tsg?g.?The entropy & volume changes at Tsgand their recovery at a new Tgare predicted.?Liquid Phase 3 is “ordered” above Tgup to a superheating temperature Tn+.?There are two critical points along the first-order line at TLL?=?0.833?×?Tm.