Synthesis of alpha,beta-Unsaturated Ketones from Natural Triterpenoids and Sterol by IBX Mediated Oxidation

Liu Yu-jiao; Huang Guo-li; Li Hao-liang; Chen Ye-gao

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Synthesis of alpha,beta-Unsaturated Ketones from Natural Triterpenoids and Sterol by IBX Mediated Oxidation

机译：通过IBX介导的氧化来合成来自天然三萜类固醇和甾醇的α，β-不饱和酮

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来源
《Chemistry of Natural Compounds》 |2019年第2期|共3页
作者
Liu Yu-jiao; Huang Guo-li; Li Hao-liang; Chen Ye-gao;
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作者单位

Yunnan Normal Univ Sch Chem &

Chem Engn Kunming 650500 Yunnan Peoples R China;

Yunnan Normal Univ Sch Chem &

Chem Engn Kunming 650500 Yunnan Peoples R China;

Yunnan Normal Univ Sch Chem &

Chem Engn Kunming 650500 Yunnan Peoples R China;

Yunnan Normal Univ Sch Chem &

Chem Engn Kunming 650500 Yunnan Peoples R China;

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正文语种 eng
中图分类化学;
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1. Synthesis of alpha,beta-Unsaturated Ketones from Natural Triterpenoids and Sterol by IBX Mediated Oxidation [J] . Liu Yu-jiao, Huang Guo-li, Li Hao-liang, Chemistry of Natural Compounds . 2019,第2期

机译：通过IBX介导的氧化来合成来自天然三萜类固醇和甾醇的α，β-不饱和酮
2. Synthesis of novel optically pure quinolyl-beta-amino alcohol derivatives from 2-amino thiophenol and chiral alpha-acetylenic ketones and their IBX-mediated oxidative cleavage to N-Boc quinolyl carboxamides [J] . Cabarrocas G., Maestro M., Mahia J., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2001,第13期

机译：由2-氨基苯硫酚和手性α-炔基酮合成新型光学纯喹啉基-β-氨基醇衍生物及其IBX介导的氧化裂解为N-Boc喹啉基羧酰胺
3. Iodine-mediated Z-selective oxidation of ketones to alpha,beta-unsaturated esters:synthesis and mechanistic studies [J] . Michael J.Zacuto, Dongwei Cai Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第48期

机译：碘介导的Z酮选择性氧化为α，β-不饱和酯的合成和机理研究
4. Catalytic 1,4-Reduction of alpha,beta-Unsaturated Ketones and Application to Asymmetric Synthesis of Warfarin [C] . Yasunori Tsuchiya, Ken-ichi Moriya, Christine Beemelmanns Symposium on Organometallic Chemistry . 2006

机译：催化1,4-减少α，β-不饱和酮和施用于Warfarin的不对称合成
5. The epoxidation of dienes, alpha,beta-unsaturated ketones, alpha,beta-unsaturated esters and vinyl esters by dimethyldioxirane. [D] . Chen, Hsinhung. 2001

机译：二烯，α，β-不饱和酮，α，β-不饱和酯和乙烯基酯被二甲基二环氧乙烷环氧化。
6. Lipoprotein cholesterol uptake mediates up-regulation of bile-acid synthesis by increasing cholesterol 7alpha-hydroxylase but not sterol 27-hydroxylase gene expression in cultured rat hepatocytes. [O] . S M Post, J Twisk, L van der Fits, 1999

机译：脂蛋白胆固醇的摄取通过增加培养的大鼠肝细胞中的胆固醇7α-羟化酶而不是固醇27-羟化酶基因表达来介导胆汁酸合成的上调。
7. Magnesium Salt-Induced Opening of alpha;, beta;-Epoxy Sulfoxides : A Synthesis of alpha;-Chloro Ketones, alpha;-Alkoxy Ketones, and alpha;, beta;-Unsaturated Ketones from Carbonyl Compounds through alpha;, beta;-Epoxy Sulfoxides [O] . TSUYOSHI SATOH, ATSUSHI SUGIMOTO, KOJI YAMAKAWA 1987

机译：镁盐诱导的α，β-环氧亚砜的开口：通过α，β-环氧亚砜的羰基化合物合成α-氯酮，α-烷氧基酮和α，β-不饱和酮

Synthesis of alpha,beta-Unsaturated Ketones from Natural Triterpenoids and Sterol by IBX Mediated Oxidation

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