Theoretical Study of the Mechanism for Direct Addition of Hydride to CO_2 on Ruthenium Complexes: Nature of Ru-H Bond and Effect of Hydrogen Bonding

Jun Li; Sha Liu; Xiaohua Lu

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Theoretical Study of the Mechanism for Direct Addition of Hydride to CO_2 on Ruthenium Complexes: Nature of Ru-H Bond and Effect of Hydrogen Bonding

机译：将氢化物直接加入CO_2对钌配合物的理论研究：Ru-H键性的性质及氢键的作用

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来源
《Bulletin of the Chemical Society of Japan 》 |2016年第8期| 共6页
作者
Jun Li; Sha Liu; Xiaohua Lu;
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作者单位

State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemistry and Chemical Engineering Nanjing Tech University Nanjing 210009 China;

State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemistry and Chemical Engineering Nanjing Tech University Nanjing 210009 China;

State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemistry and Chemical Engineering Nanjing Tech University Nanjing 210009 China;

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正文语种 eng
中图分类化学 ;
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1. Theoretical Study of the Mechanism for Direct Addition of Hydride to CO_2 on Ruthenium Complexes: Nature of Ru-H Bond and Effect of Hydrogen Bonding [J] . Jun Li, Sha Liu, Xiaohua Lu Bulletin of the Chemical Society of Japan . 2016 ,第8期

机译：将氢化物直接加入CO_2对钌配合物的理论研究：Ru-H键性的性质及氢键的作用
2. Mechanisms of the H_2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes [J] . Sean E. Clapham, Alen Hadzovic, Robert H. Morris Coordination chemistry reviews . 2004 ,第21a24期

机译：氢化钌配合物催化极性键的H_2加氢和转移加氢机理
3. H-X bond activation via hydrogen transfer to hydride in ruthenium N-heterocyclic carbene complexes: Density functional and synthetic studies [J] . Chatwin SL, Davidson MG, Doherty C, Organometallics . 2006 ,第1期

机译：通过氢转移至钌N-杂环卡宾配合物中的H-X键活化：密度泛函和合成研究
4. Theoretical Study of Tungsten Dihydride Silyl Complexes: New Insight of Their Bonding Nature and Flexible Behavior [C] . Mausumi Ray, Yoshihide Nakao, Hirofomi Sato Symposium on Organometallic Chemistry . 2008

机译：钨二羟基甲硅烷基配合物的理论研究：其粘接性质的新洞察力和灵活的行为
5. Mechanisms of electron transfer and hydrogen activation in selected triruthenium clusters with multiple bridging ligands. Part I. The attenuation of radical reactivity in triruthenium trihydrido(alkylidyne) clusters. Electrochemistry and kinetics of decomposition of the 47-electron cluster radical, via a disproportionation path. Part II. The activation of molecular hydrogen at transition metal centers via kinetics and mechanism of reversible oxidative addition of hydrogen across the metal-metal bond of (mu-hydrogen)(2)Ruthenium(3)(Carbon monoxide)(8)(mu-phosphorus(t-BU)(2))(2). [D] . Bierdeman, David John. 2000

机译：具有多个桥联配体的选定三钌簇中电子转移和氢活化的机理。第一部分。三氢三钌（亚烷基）簇中自由基反应性的减弱。通过歧化路径分解47电子簇自由基的电化学和动力学。第二部分通过（mu-hydrogen）（2）钌（3）（一氧化碳）（8）（mu-phosphorus（）的金属-金属键上氢的可逆氧化加成反应的动力学和机理激活过渡金属中心的分子氢t-BU）（2））（2）。
6. Raman and Theoretical Study of M2(dmp)4 M = Cr (natural abundance Cr 50Cr and 54Cr) and Mo; dmp = 26-dimethoxyphenyl. The Nature of Bonding in Complexes Containing ‘Supershort’ Metal-Metal Bonds [O] . Ryan E. Da Re, Judith L. Eglin, Christin N. Carlson, -1

机译：拉曼和m2（Dmp）的理论研究4 m =铬（天然丰度的Cr50Cr和54Cr）和mo; Dmp = 26-二甲氧基苯基。粘接的复合物中的含自然超短金属 - 金属键
7. Attenuation of intramolecular Ru-H⋯H-N dihydrogen bonding in aminocyclopentadienyl ruthenium hydride complexes containing phosphite ligands [O] . Lam YF, Yin C, Yeung CH, 2002

机译：含亚磷酸酯配体的氨基环戊二烯基氢化钌络合物中分子内Ru-H⋯H-N二氢键的衰减
8. Mechanism of Oxidative Addition of Cyclopentadienyl-Rhodium Complexes to Carbon-Hydrogen and Carbon-Carbon Bonds [R] . Periana-Pillai, R. A. 1985

机译：环戊二烯基 - 铑配合物氧化加成碳氢和碳 - 碳键的机理

Theoretical Study of the Mechanism for Direct Addition of Hydride to CO_2 on Ruthenium Complexes: Nature of Ru-H Bond and Effect of Hydrogen Bonding

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