Crystal chemistry of mimetite, Pb-10(AsO4 )(6)Cl1.48O0.26, and finnemanite, Pb-10(AsO3)(6)Cl-2

摘要

The crystal chemistries of synthetic mimetite, Pb-10(As5+O4)(6)(Cl2-xOx/2), a neutral apatite, and finnemanite, Pb-10(As3+O3)(6)Cl-2, a reduced apatite, were characterized using a combination of X-ray powder diffraction, neutron diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Both phases conform to hexagonal P6(3)/m symmetry; however, the temperature-driven transformation of clinomimetite to mimetite described earlier was not confirmed. The average mimetite structure is best described through the introduction of partially occupied oxygen sites. A better understanding of the mixed arsenic speciation in apatites can guide the formulation of waste form ceramics and improve models of long-term durability after landfill disposal.