Highly efficient and eco-friendly protocol to functionalized imidazoles via ring-opening of alpha-nitro epoxides

Guo Xiao; Shao Jiaan; Liu Huan; Chen Binhui; Chen Wenteng; Yu Yongping

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Highly efficient and eco-friendly protocol to functionalized imidazoles via ring-opening of alpha-nitro epoxides

机译：通过α-硝基环氧化物的开环功能高效且生态友好的协议通过开环开环

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摘要

A simple and direct synthesis of functionalized imidazoles from alpha-nitro-epoxides and amidines was developed. This reaction could proceed smoothly in a highly efficient and eco-friendly manner in moderate to excellent yields. A plausible mechanism has also been proposed.

机译：开发了α-硝基 - 环氧化物和脒的官能化咪唑的简单和直接合成。这种反应可以以高效和生态的方式平稳地进行中度至优异的产量。也提出了一种合理的机制。

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《RSC Advances》 |2015年第64期|共4页
作者
Guo Xiao; Shao Jiaan; Liu Huan; Chen Binhui; Chen Wenteng; Yu Yongping;
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作者单位

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

Zhejiang Univ Zhejiang Prov Key Lab Anticanc Drug Res Coll Pharmaceut Sci Hangzhou 310058 Zhejiang Peoples R China;

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正文语种 eng
中图分类化学;
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1. Highly efficient and eco-friendly protocol to functionalized imidazoles via ring-opening of alpha-nitro epoxides [J] . Guo Xiao, Shao Jiaan, Liu Huan, RSC Advances . 2015,第64期

机译：通过α-硝基环氧化物的开环功能高效且生态友好的协议通过开环开环
2. Stereoselective Syntheses of Highly Functionalized Imidazolidines and Oxazolidines via Ring-Opening Cyclization of Activated Aziridines and Epoxides with Amines and Aldehydes [J] . Tarannum Saima, Sk Sahid, Das Subhomoy, The Journal of Organic Chemistry . 2020,第2期

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3. Si-Imidazole-HSO4 Functionalized Magnetic Fe3O4 Nanoparticles as an Efficient and Reusable Catalyst for the Regioselective Ring Opening of Epoxides in Water [J] . Eshagh Rezaee Nezhad, Ezatallah Pourmalekshahi Nanochemistry Research . 2016,第1期

机译：Si-咪唑-HSO4官能化的磁性Fe3O4纳米颗粒可作为水中环氧的区域选择性开环的高效且可重复使用的催化剂
4. Sonocatalysis in solvent free conditions: an efficient eco-friendly methodology to prepare N-alkyl imidazoles using zeolites [C] . V.Calvino-Casilda, R.M.Martin-Aranda, W.N.Lau, the International Zeolite Symposium . 2005

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5. Development and mechanistic studies of a highly active and selective oligomeric (Salen)cobalt(III) catalyst for asymmetric epoxide ring-opening reactions [D] . White, David Emery 2006

机译：用于不对称环氧化物开环反应的高活性和选择性低聚（Salen）钴（III）催化剂的开发和机理研究
6. Silk protein nanofibers for highly efficient eco-friendly optically translucent and multifunctional air filters [O] . Kyungtaek Min, Sookyoung Kim, Sunghwan Kim -1

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7. Brønsted acidic ionic liquid catalyzed an efficient and eco-friendly protocol for the synthesis of 2,4,5-trisubstituted-1H-imidazoles under solvent-free conditions [O] . Janardhan Banothu, Rajitha Gali, Ravibabu Velpula, 2017

机译：布朗斯台德酸性离子液体催化一种有效且环保的方案，用于在无溶剂条件下合成2,4,5-三取代-1H-咪唑

Highly efficient and eco-friendly protocol to functionalized imidazoles via ring-opening of alpha-nitro epoxides

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