Triphenylphosphine-assisted highly sensitive fluorescent chemosensor for ratiometric detection of palladium in solution and living cells

摘要

Accurate and sensitive detection of palladium (Pd) is essential for both environmental and human health applications. This paper describes a triphenylphosphine (PPh3)-assisted highly sensitive fluorescent chemosensor for ratiometric detection of Pd2+ concentrations up to 300 nM with an LOD of 1 nM. During the detection, PPh3 plays a crucial role in improving the sensitivity of this chemosensor. The chemosensor also has suitable water-solubility which allows detection of Pd2+ in solution. Our studies show that it exhibits excellent selectivity toward Pd2+ and undergoes a color change from colorless to yellow to allow visual detection of Pd2+. Besides detection in solution, this chemosensor also shows great potential as an imaging reagent to detect Pd2+ as low as 0.03 ppm in diverse cells.