The Crystal Structure of[Li8Ti_(10)F_(36)O4(C5Me5)4(thf)8]

摘要

The crystals of the cluster[Li8Ti_(10)F_(36)O4(C5Me5)4(thf)8]3 were isolated as the product of hydrolysis of[{(C5Me5)TiF3}4(LiF)2(thf)2]2.The metal atoms in the cluster are six-coordinate(Ti and Li),or four-coordinate(Li).The oxido ligands form unsymmetrical oxido bridges Ti=O-Ti with a double-bond character.The mechanism of the cluster formation is proposed.