Facile preparation of superhydrophobic and oleophobic surfaces via the combination of Cu(0)‐mediated reversible‐deactivation radical polymerization and click chemistry

Enayati Mojtaba; Abbaspourrad Alireza

摘要

ABSTRACT > The fabrication of novel hydrophobic, superhydrophobic, and oleophobic surfaces on glass using nanosilica particles modified with polymer brushes prepared via surface initiated Cu(0)‐mediated reversible‐deactivation radical polymerization was demonstrated. Monomers including n ‐butyl acrylate, 2,2,2‐trifluoroethyl methacrylate, and 1,1,1,3,3,3‐hexafluoroisopropyl acrylate were used to synthesize a series of nanosilica–polymer organic/inorganic hybrid materials. Products were analyzed using infrared spectroscopy, thermogravimetric analysis, scanning and transmission electron microscopy. The coated nanosilica showed core–shell structures that contains polymer brushes up to 67 wt %. The application of these particles for modifying surface wettability was examined by covalently attaching them to glass via a recently developed one‐pot “grafting to” methodology using “thio‐bromo click” chemistry. Atomic force microscopy topographic images show up to 25 times increase in roughness of the coated glass compared to blank glass sample. Contact angle measurements showed that nanosilica coated with PBA and PTFEM produced hydrophobic glass surfaces, while a superhydrophobic and oleophobic surface was generated using nanosilica functionalized with PHFIPA. This novel methodology can produce superhydrophobic and oleophobic surfaces in an easy and fast way without the need for tedious and time‐consuming processes, such as layer‐by‐layer deposition, high temperature calcination, and fluorinated oil infusion. ? 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract xmlns =“http://www.wiley.com/namespaces/wiley”type =“main”> <title type =“main”>摘要</ title> >新疏水，超疏水性的制作玻璃上使用用表面引入的Cu（0）介导的Cu（0）介导的可逆性 - 去激活自由基聚合来改性用聚合物刷改性的纳米硅颗粒上的疏油表面。包括丙烯酸酯，2,2,2-三氟乙酯和1,1,1,3,3,3-六氟异丙基丙烯酸酯，包括丙烯酸酯，2,2,2-三氟乙酯和1,1,1,3,3,3,3,3-六氟异丙基丙烯酸酯。合成一系列纳米碱 - 聚合物有机/无机混合材料。使用红外光谱，热重分析，扫描和透射电子显微镜分析产品。涂覆的纳米硅藻显示核壳结构，其含有高达67wt％的聚合物刷子。通过使用“Thio-Bromo点击”化学将它们通过最近开发的单罐“嫁接至”方法共价将它们与玻璃共价连接到玻璃来检查这些颗粒来改变表面润湿性。与空白玻璃样品相比，原子力显微镜地形图像显示涂层玻璃粗糙度增加25倍。接触角测量表明，纳米菌涂有PBA和PTFEM产生的疏水玻璃表面，而使用用pHFIPA官能化的纳米硅藻产生超疏水和疏油表面。这种新的方法可以以简单快速的方式生产超疏水和疏油表面，而无需繁琐且耗时的方法，例如层层沉积，高温煅烧和氟化油输注。还是2018 Wiley期刊，Inc.J.Colom。 SCI。，A部分：polym。化学。 2018 </ b> </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35621/'>《Journal of Polymer Science, Part A. Polymer Chemistry 》</a> <b style="margin: 0 2px;">|</b><span>2018年第15期</span><b style="margin: 0 2px;">|</b> <span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Enayati Mojtaba&option=202" target="_blank" rel="nofollow">Enayati Mojtaba;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abbaspourrad Alireza&option=202" target="_blank" rel="nofollow">Abbaspourrad Alireza;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Food Science College of Agriculture and Life SciencesCornell UniversityIthaca New York;</p> <p>Department of Food Science College of Agriculture and Life SciencesCornell UniversityIthaca New York;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1184.html" title="有机化学">有机化学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cu(0)‐mediated reversible‐deactivation radical polymerization&option=203" rel="nofollow">Cu(0)‐mediated reversible‐deactivation radical polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluoropolymers&option=203" rel="nofollow">fluoropolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanoparticles&option=203" rel="nofollow">nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oleophobic&option=203" rel="nofollow">oleophobic;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=superhydrophobic&option=203" rel="nofollow">superhydrophobic;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surface initiated living polymerization&option=203" rel="nofollow">surface initiated living polymerization;</a> </p> <div class="translation"> 机译：Cu（0） - 介导的可逆停用自由基聚合;含氟聚合物;纳米颗粒;疏油性;超疏水;表面发起的活性聚合; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020726151.html">Facile preparation of superhydrophobic and oleophobic surfaces via the combination of Cu(0)‐mediated reversible‐deactivation radical polymerization and click chemistry</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Enayati Mojtaba&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Enayati Mojtaba,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abbaspourrad Alireza&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Abbaspourrad Alireza </a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. 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