Strategy for rational control of stereosequence in free radical polymerization of acrylates

机译：丙烯酸酯自由基聚合的理性控制理性控制策略

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ABSTRACT > Radical polymerization of cyclic analogs of acrylates, ( S )‐ and ( R )‐2‐isopropyl‐5‐methylene‐1,3‐dioxolan‐4‐ones ( 1S and 1R ), successfully afforded a functional polymer having the tacticity continuously controlled from 29% to ～100% of meso triad ( mm ) over a wide range of temperature only by changing the molar ratio of 1S / 1R in feed. Plot of the number fractions of the triad versus diad of poly( 1 ) was in good agreement with the Bernoulli statistics. In the polymerization in chiral solvents having analogs structure of the monomers, the tacticity and specific rotation of the resulting polymer were specifically varied depending on the structure and concentration of the solvents. Model propagation reaction at dimeric radical calculated with density functional theory reproduced a methodical induction of the chirality to the main chain from the branched chiral monomeric unit, which supports the experimental expectations. It is remarkable that the ceiling temperature of 1 is tremendously high, for example, 193 °C in [ 1 ( ee ?=?72.6%)]?=?0.05 mol/L, and the isospecific polymerization is maintained even at such a high temperature, which enabled the control of polymer tacticity over a wide range of temperature. The mechanism of the stereosequence in radical polymerization was discussed experimentally and theoretically. ? 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56 , 184–193 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespace/wiley”type =“main”> <title type =“main”>丙烯酸酯环状类似物的自由基聚合，（ s </ i>） - （ r r℃）-2-异丙基-5-亚甲基-1,3-二氧烷-4-α（ 1s </ b>和< B> 1r </ b>），通过改变摩尔仅通过改变摩尔，成功地提供了具有典型术的功能性聚合物，该官能团在很宽的温度下连续地控制29％至约100％的MESO TRIAD（ mm </ i）饲料中 1s / b> / 1r </ b>的比例。与伯努利统计数据吻合的三合会数量的三合会数量分数的曲线图。在具有单体的类似物结构的手性溶剂中的聚合中，取决于溶剂的结构和浓度，特异性变化了所得聚合物的术术和特异性旋转。用密度函数理论计算的二聚体自由基的模型繁殖反应再现了从支链手性单体单元中对主链进行手性的方法诱导，这支持了实验期望。值得注意的是， 1 / b>的上限温度非常高，例如，193℃（[e> ee </ i> = = 72.6％））？= 0.05mol / L，即使在这种高温下也保持了不受特异性的聚合，使得在宽范围的温度下使聚合物转发的控制能够控制。实验和理论上讨论了自由基聚合中的立体术机制。还是2017 Wiley期刊，Inc.J.Colom。 SCI。，A部分：polym。化学。 2018 </ b>， 56 </ i>，184-193 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35621/'>《Journal of Polymer Science, Part A. Polymer Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第2期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tanaka Hitoshi&option=202" target="_blank" rel="nofollow">Tanaka Hitoshi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maki Kazuyoshi&option=202" target="_blank" rel="nofollow">Maki Kazuyoshi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Matsubara Yoshitaka&option=202" target="_blank" rel="nofollow">Matsubara Yoshitaka;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Technology and Science University of Tokushima 2‐1 Minamijosanjima‐choTokushima 770‐8506 Japan;</p> <p>Graduate School of Advanced Technology and ScienceUniversity of Tokushima 2‐1 Minamijosanjima‐choTokushima 770‐8506 Japan;</p> <p>Graduate School of Advanced Technology and ScienceUniversity of Tokushima 2‐1 Minamijosanjima‐choTokushima 770‐8506 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1184.html" title="有机化学">有机化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=acrylate&option=203" rel="nofollow">acrylate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=captodative&option=203" rel="nofollow">captodative;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lactic acid&option=203" rel="nofollow">lactic acid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=stereospecific radical polymerization&option=203" rel="nofollow">stereospecific radical polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tacticity&option=203" rel="nofollow">tacticity;</a> </p> <div class="translation"> 机译：丙烯酸酯;Captodative;乳酸;立体特异性自由基聚合;术文; </div> </li> <li> <span class="lefttit">入库时间</span> <span>2022-08-19 19:48:03</span> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020726005.html">Strategy for rational control of stereosequence in free radical polymerization of acrylates</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tanaka Hitoshi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tanaka Hitoshi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maki Kazuyoshi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Maki Kazuyoshi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Matsubara Yoshitaka&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Matsubara Yoshitaka </a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. 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<span> <a href="/conference-cn-33266/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会'99高分子学术论文报告会 </a> <span> <span> . 1999</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031543694.html">退化碘转移自由基聚合(DITP)合成聚丙烯酸酯二醇与聚丙烯酸酯-丙烯酸二醇及其制备水性聚氨酯的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈昕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈昕</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120111845260.html">聚合物的物理性质预测装置、存储介质、及聚合物的物理性质预测方法</a> <b>[P]</b> . <span> 中国专利： CN111819441A </span> <span> . 2020-10-23</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061204112568.html">具有独特物理性质的氨基甲酸酯丙烯酸酯聚合物</a> <b>[P]</b> . <span> 中国专利： CN106471031B </span> <span> . 2020.11.24</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130456031216.html">Polymerization process for the preparation of resins containing acrylate homopolimérico free radical polymerization for the preparation of thermoplastic containing acrylate homopolymer and resimaPolym</a> <b>[P]</b> . <span> 外国专利：  BR9507868A </span> <span> . 1997-09-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备含丙烯酸酯均聚物的树脂的聚合方法自由基聚合制备含丙烯酸酯均聚物的热塑性树脂和Resima自由基聚合用于制备热塑性树脂嵌段共聚物或含均聚物的多嵌段共聚物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130434253314.html">PROCESS FOR THE CONTROLLED RADICAL POLYMERIZATION OR COPOLYMERIZATION OF ETHYLENE UNDER HIGH PRESSURE IN THE PRESENCE OF INITIATING FREE RADICALS AND OF CONTROLLING INDOLINE NITROXIDE RADICALS</a> <b>[P]</b> . <span> 外国专利：  KR100742143B1 </span> <span> . 2007-07-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：存在自由基和控制二氧化氮自由基的高压下乙烯的受控自由基聚合或共聚过程 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130442598888.html">Process for the controlled radical polymerization or copolymerization of ethylene under high pressure in the presence of initiating free radicals and of controlling indoline nitroxide radicals</a> <b>[P]</b> . <span> 外国专利：  US6706832B2 </span> <span> . 2004-03-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在引发自由基和控制二氢吲哚氮氧化物自由基存在下高压下乙烯受控自由基聚合或共聚的方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> 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