Surface modification for nano‐lignocellulose fiber through vapor‐phase‐assisted surface polymerization

机译：通过气相辅助表面聚合的纳米木纤维素纤维表面改性

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ABSTRACT > This study addresses the inherent issues surrounding surface modification methods of nanofibers and proposes an environmentally friendly and less toxic strategy for the surface modification of hydrophilic nanofiber. From the continuation of our previous work, which discussed the easy production of nanofiber (average size: 127?nm) from oil palm mesocarp fiber (OPMF), in this work, the surface of nanofibers (M‐IL‐OPMF) were modified through vapor‐phase‐assisted surface polymerization (VASP) to improve the affinity of interface between the polymer grafted M‐IL‐OPMF and non‐polar matrix. VASP of ε‐caprolactone was successfully proceeded from the [M‐IL‐OPMF] at 70?°C for 24?h and 72?h, and compositions were estimated to be 35.7% fiber/64.3% polymer and 27.8% fiber/72.2% polymer. To confirm the grafting of PCL, size‐exclusion chromatography (SEC) and Fourier transform infrared (FT‐IR) spectroscopy, thermogravimetry (TG), and dispersibility test in hydrophobic solvent were carried out. ? 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57 , 2575–2580 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 该研究解决了纳米纤维表面修饰方法的固有问题，并提出了对亲水纳米纤维的表面改性的环保和较小的毒性策略。从我们以前的工作的延续，讨论了纳米纤维（平均尺寸：127？NM）的易于生产，在这项工作中，通过纳米纤维（M-IL-OPMF）的表面通过气相辅助表面聚合（VASP）以改善聚合物接枝M-IL-OPMF和非极性基质之间的界面的亲和力。将ε-己内酯的VASP从70？℃的[M-IL-OPMF]成功进行24℃，72℃，估计组合物为35.7％纤维/ 64.3％聚合物，27.8％纤维/ 72.2 ％聚合物。为了确认PCL的接枝，尺寸排阻色谱（SEC）和傅立叶变换红外（FT-IR）光谱，进行热重试剂（TG）和疏水溶剂中的分散性试验。还是2019 Wiley期刊，Inc.J.Colom。 SCI。，A部分：polym。化学。 2019 </ b> 那 57 </ i> ，2575-2580. </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35621/'>《Journal of Polymer Science, Part A. Polymer Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第24期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eksiler Kubra&option=202" target="_blank" rel="nofollow">Eksiler Kubra;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andou Yoshito&option=202" target="_blank" rel="nofollow">Andou Yoshito;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ariffin Hidayah&option=202" target="_blank" rel="nofollow">Ariffin Hidayah;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shirai Yoshihito&option=202" target="_blank" rel="nofollow">Shirai Yoshihito;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Biological Functions and Engineering Graduate School of Life Science and Systems EngineeringKyushu Institute of Technology 2‐4 Hibikino Wakamatsu‐ku KitakyushuFukuoka 808‐0196 Japan;</p> <p>Department of Biological Functions and Engineering Graduate School of Life Science and Systems EngineeringKyushu Institute of Technology 2‐4 Hibikino Wakamatsu‐ku KitakyushuFukuoka 808‐0196 Japan;</p> <p>Laboratory of Biopolymer and DerivativesInstitute of Tropical Forestry and Forest Products Universiti Putra Malaysia43400 UPM Serdang Selangor Malaysia;</p> <p>Department of Biological Functions and Engineering Graduate School of Life Science and Systems EngineeringKyushu Institute of Technology 2‐4 Hibikino Wakamatsu‐ku KitakyushuFukuoka 808‐0196 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1184.html" title="有机化学">有机化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fibrillation&option=203" rel="nofollow">fibrillation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oil palm mesocarp fiber&option=203" rel="nofollow">oil palm mesocarp fiber;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polycaprolactone&option=203" rel="nofollow">polycaprolactone;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surface modification&option=203" rel="nofollow">surface modification;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=vapor‐phase‐assisted surface polymerization&option=203" rel="nofollow">vapor‐phase‐assisted surface polymerization;</a> </p> <div class="translation"> 机译：纤维化;油棕Mesocarp纤维;聚己内酯;表面改性;气相辅助表面聚合; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020725902.html">Surface modification for nano‐lignocellulose fiber through vapor‐phase‐assisted surface polymerization</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eksiler Kubra&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Eksiler Kubra,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andou Yoshito&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Andou Yoshito,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ariffin Hidayah&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ariffin Hidayah,</a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. 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</b><a class="enjiyixqcontent" href="/patent-detail/06130432376826.html">SURFACE MODIFICATION OF NANOPARTICLES BY PHOSPHORUS-CONTAINING COMPOUNDS IN THE VAPOR PHASE</a> <b>[P]</b> . <span> 外国专利：  WO2008017663A3 </span> <span> . 2008-03-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：气相中含磷化合物对纳米颗粒的表面修饰 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704020725902','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> 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