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Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene

机译：通过阴离子，阳离子和激进活性物种：末端碳 - 卤素键，用于“受控”/苯乙烯的活性聚合

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ABSTRACT > In this work, we examined the synthesis of novel block (co)polymers by mechanistic transformation through anionic, cationic, and radical living polymerizations using terminal carbon–halogen bond as the dormant species. First, the direct halogenation of growing species in the living anionic polymerization of styrene was examined with CCl <sub>4</sub> to form a carbon–halogen terminal, which can be employed as the dormant species for either living cationic or radical polymerization. The mechanistic transformation was then performed from living anionic polymerization into living cationic or radical polymerization using the obtained polymers as the macroinitiator with the SnCl <sub>4</sub> / n ‐Bu <sub>4</sub> NCl or RuCp * Cl(PPh <sub>3</sub> )/Et <sub>3</sub> N initiating system, respectively. Finally, the combination of all the polymerizations allowed the synthesis block copolymers including unprecedented gradient block copolymers composed of styrene and p ‐methylstyrene. ? 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57 , 465–473 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><抽象类型=“主要”的xml：郎=“EN”> <标题类型=“主”>摘要</ TITLE> >在这项工作中，我们检查了新的嵌段（共）聚合物的通过机械变换的合成通过阴离子，阳离子和自由基活性聚合用末端碳 - 卤素键的休眠种。首先，生长物种的在苯乙烯的活性阴离子聚合的直接卤化物与CCl <子> 4 </子>检查，以形成碳 - 卤素，其中终端可以被用作休眠种为任一活性阳离子聚合或自由基聚合。的机械变换然后从活性阴离子聚合进行到使用所获得的聚合物作为与所述的SnCl <子>大分子引发剂活性阳离子聚合或自由基聚合4 </子> / 名词</ i>的-Bu <子> 4 < /子>的NCI或RuCp <SUP> * </ SUP>氯（PPH <子> 3 </子>）/ ET <子> 3 </子> n均为引发体系。最后，所有的聚合反应的组合所允许的合成嵌段共聚物，包括苯乙烯组成的前所未有的梯度的嵌段共聚物和 P </ i>的甲基苯乙烯。还是2018 Wiley期刊，Inc.J.Colom。 SCI。，A部分：polym。化学。 <B> 2019 </ B>，<I> 57 </ i>的，465-473 </ p> </抽象> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35621/'>《Journal of Polymer Science, Part A. Polymer Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第3期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Satoh Kotaro&option=202" target="_blank" rel="nofollow">Satoh Kotaro;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mori Yuya&option=202" target="_blank" rel="nofollow">Mori Yuya;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kamigaito Masami&option=202" target="_blank" rel="nofollow">Kamigaito Masami;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Molecular and Macromolecular Chemistry Graduate School of EngineeringNagoya UniversityFuro‐cho Chikusa‐ku Nagoya 464‐8603 Japan;</p> <p>Department of Molecular and Macromolecular Chemistry Graduate School of EngineeringNagoya UniversityFuro‐cho Chikusa‐ku Nagoya 464‐8603 Japan;</p> <p>Department of Molecular and Macromolecular Chemistry Graduate School of EngineeringNagoya UniversityFuro‐cho Chikusa‐ku Nagoya 464‐8603 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1184.html" title="有机化学">有机化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon–halogen bond&option=203" rel="nofollow">carbon–halogen bond;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=living anionic polymerization&option=203" rel="nofollow">living anionic polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=living cationic polymerization&option=203" rel="nofollow">living cationic polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=living radical polymerization&option=203" rel="nofollow">living radical polymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanistic transformation&option=203" rel="nofollow">mechanistic transformation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=styrene&option=203" rel="nofollow">styrene;</a> </p> <div class="translation"> 机译：碳 - 卤素键;生活阴离子聚合;生物阳离子聚合;生活自由基聚合;机械转换;苯乙烯; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020725717.html">Direct through anionic, cationic, and radical active species: Terminal carbon–halogen bond for “controlled”/living polymerizations of styrene</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Satoh Kotaro&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Satoh Kotaro,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mori Yuya&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mori Yuya,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kamigaito Masami&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kamigaito Masami </a> <a href="/journal-foreign-35621/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Polymer Science, Part A. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘青&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘青</a> <span> <a href="/journal-cn-56916/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子学报 </a> </span> <span> . 2000</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296022883.html">非理想活性聚合反应动力学的一般模型.双活性物种体系的稳态理论</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=颜德岳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 颜德岳</a> <span> <a href="/journal-cn-56862/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料科学与工程 </a> </span> <span> . 2000</span><span>,第2期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-11387_thesis/02022359286.html">侧基官能性乙烯基醚阳离子活性聚合与乙烯基醚阳离子光固化体系</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=庞玉莲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 庞玉莲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邹应全&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邹应全</a> <span> <a href="/conference-cn-11387/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2011先进影像材料与前沿技术学术论坛 </a> <span> <span> . 2011</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315058616.html">苯乙炔钯配合物活性聚合异腈单体的卤素效应</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王亚琪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王亚琪</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120112716228.html">电活性聚合物器件和用于制造这种电活性聚合物器件的方法</a> <b>[P]</b> . <span> 中国专利： CN112771683A </span> <span> . 2021-05-07</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120110833087.html">包含至少一种阴离子表面活性剂、至少两种特定的非离子表面活性剂、至少一种两性表面活性剂以及至少一种特定的阳离子聚合物的组合物</a> <b>[P]</b> . <span> 中国专利： CN108348428A </span> <span> . 2018-07-31</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130441111679.html">MACROMONOMER DERIVED FROM NORBORNENE-BASED MONOMER HAVING HALOGEN GROUP CAPABLE OF INDUCING RADICAL POLYMERIZATION AT ITS TERMINAL, NORBORNENE POLYMER HAVING GROUP CAPABLE OF INDUCING RADICAL POLYMERIZATION AT SIDE CHAIN AND NORBORNENE POLYMER PRODUCED BY GRAFT REACTION OF THE MACROMONOMER USING ACRYLATE MONOMER OR STYRENE MONOMER, AND METHOD FOR PRODUCING THEM</a> <b>[P]</b> . <span> 外国专利：  JP2005126598A </span> <span> . 2005-05-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：从基于降冰片烯的单体衍生的大分子单体具有能够在其末端引发自由基聚合的卤代基团，降冰片烯聚合物的基团能够在单体链上通过单体或单体的聚合反应在单体的链上引发自由基聚合，并通过单体或缩聚反应使之还原用于生产它们 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130439093691.html">Rubber-modified styrene polymer production, for molding, film, fiber or foam, involves producing rubber by anionic dispersion polymerization, dissolving in styrene monomer without removing medium and anionic or free radical polymerization</a> <b>[P]</b> . <span> 外国专利：  DE10330935A1 </span> <span> . 2005-02-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：橡胶改性的苯乙烯聚合物的生产，用于模制，薄膜，纤维或泡沫，涉及通过阴离子分散聚合生产橡胶，将其溶于苯乙烯单体而不除去介质以及阴离子或自由基聚合 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130445904414.html">Production of polymers by controlled living radical polymerization of vinyl monomers in aqueous solution involves using the monomers, initiator or radical trapping species in the form of a cyclodextrin complex</a> <b>[P]</b> . <span> 外国专利：  DE10027744A1 </span> <span> . 2001-12-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过水溶液中乙烯基单体的受控活性自由基聚合生产聚合物涉及使用环糊精配合物形式的单体，引发剂或自由基捕获剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704020725717','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> 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