H-1 NMR of paramagnetic Lanthanide(III) complexes of trifluoroacetylacetone and 2,2 '-Bipyridyl and 4f-4f absorption studies

摘要

A series of anhydrous eight-coordinate air and moisture stable lanthanide (Ill) complexes of 1,1,1-trifluoro-2,4-pentanedione (tfaa) and 2,2'-bipyridyl (bpy) of the type [Ln(tfaa)(3)(bpy)] [Ln = La (1), Nd (2), Ho (3), Er (4), Yb (5) and Lu (6)] have been synthesized in high yield by a one-step method and characterized by elemental analyses, ESI-MS+, TGA, DTA IR and H-1 NMR spectroscopy. The NMR spectra of diamagnetic and paramagnetic complexes reveal that the bpy unit remains attached to the metal in solution. The beta-diketonate (methine and methyl) and bpy protons resonances are shifted in opposite directions in a given paramagnetic complex and the lanthanide-induced shifts are dipolar in nature. The 4f - 4f absorption spectra of the complexes of Nd(III), Er(Ill) and Ho(III) are analyzed. The hypersensitive transitions of Nd(III), Er(III) and Ho(III) complexes are sensitive to the environment (ligand/solvent), which is reflected by different oscillator strengths and distinctively different band shapes of the hypersensitive transitions. The coordination geometries of [Ln(tfaa)(3)H2O] and [Ln(tfaa)(3)(bpy)] (Ln = La and Nd) are calculated using the Sparkle/PM3 model. (C) 2018 Elsevier B.V. All rights reserved.