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Synthesis, characterization and photocatalytic activity of TiO 2/ZnO-supported phosphomolybdic acid nanocomposites

机译:TiO的合成,表征和光催化活性 2> / / ZnO-支持的磷钼酸纳米复合材料

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摘要

AbstractThree nanocomposites of phosphomolybdic acid supported on TiO2and ZnO nanoparticles were synthesized and characterized by means of FESEM, FTIR and XRD analysis. Photocatalytic activity of the synthesized nanocomposite was investigated for aniline as an organic pollutant model. Relatively, good degradation efficiency above 70% was achieved for all nanocomposites in presence of hydrogen peroxide as electron scavenger. The kinetic study showed that photocatalytic degradation of aniline followed the Langmuir-Hinshelwood model. Results showed that hydroxyl radicals and holes play an important role in photocatalytic degradation of aniline using synthesized nanocomposites. These results suggested that synthesized nanocomposites could be promising photocatalysts in the removal of aniline from aqueous solutions.Highlights?Synthesis of TiO2-supported phosphomolybdic acid nanocomposites.?Synthesis of ZnO and TiO2/ZnO -supported phosphomolybdic acid nanocomposites for the first time.?
机译:<![cdata [ 抽象 TiO 2 和ZnO纳米粒子的特征。研究了合成纳米复合物的光催化活性,以苯胺作为有机污染物模型。在作为电子清除剂的过氧化氢存在下,所有纳米复合材料都达到了70%以上的良好降解效率。动力学研究表明,苯胺的光催化降解跟随Langmuir-Hinshelwood模型。结果表明,羟基自由基和孔在使用合成纳米复合材料的光催化降解苯胺的光催化降解中起重要作用。这些结果表明,合成的纳米复合材料可以是在从水溶液中除去苯胺的光催化剂。 突出显示 < CE:PARA ID =“P0005”查看=“全部”> TiO的合成 2 -UMPORTED磷钼族酸纳米复合材料。 Zno和Tio的合成 2 / ZnO -Supported磷钼酸纳米复合材料是第一次。

著录项

  • 来源
    《Journal of Molecular Liquids》 |2018年第2018期|共8页
  • 作者单位

    Environmental Science and Technology Research Center Department of Environmental Health Engineering Shahid Sadoughi University of Medical Sciences;

    Department of Chemistry Yazd Branch Islamic Azad University;

    Environmental Science and Technology Research Center Department of Environmental Health Engineering Shahid Sadoughi University of Medical Sciences;

    Environmental Science and Technology Research Center Department of Environmental Health Engineering Shahid Sadoughi University of Medical Sciences;

    Department of Environmental Health Engineering School of Public Health Social Development &

    Health Promotion Research Center Gonabad University of Medical Sciences;

    Social Determinants of Health Research Center Department of Social Medicine School of Medicine Gonabad University of Medical Sciences;

    Department of Microbiology School of Medicine Gonabad University of Medical Sciences;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 理论物理学;
  • 关键词

    Heteropolyanions; Phosphomolybdic acid; Polyoxometalate; Photocatalytic activity; Aniline; TiO2; ZnO;

    机译:杂氮杂化;磷钼酸;聚毒酸盐;光催化活性;苯胺;TiO2;ZnO;

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