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Structural, Electrical and Dielectric Properties of Li-Ni Ferrite-Polystyrene Thin Film Nano-Composites

机译:Li-Ni铁素体 - 聚苯乙烯薄膜纳米复合材料的结构,电气和介电性能

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Lithium nickel ferrite Li0.5Ni0.5Fe2O4 was synthesized by the sol-gel auto combustion method. The prepared ferrite was mixed with polystyrene with ratio 0.25:1(FP1), 0.50:1(FP2), 0.75:1(FP3) and 1:1(FP4) to get ferrite-polystyrene composite. The synthesized samples were characterized by x-ray diffraction, dielectric and direct current resistivity measurements. The x-ray diffraction pattern shows that the polystyrene is amorphous in nature. The diffraction peaks of ferrite-polystyrene composite become sharper and narrower by increasing the ferrite filler contents. Room temperature resistivity of the composites decreased significantly from 4.63 x 10(13) Omega-cm to 3.67 x 10(9) Omega-cm with increasing ferrite content and temperature dependent resistivity decreased with increasing temperature. The dielectric constant increased as the concentration of ferrite was increased in the base sample. A maximum value of 23.60 was achieved for the last sample. Conversely, the increase in frequency results from the decrease in dielectric constant followed the Maxwell-Wagner model.
机译:通过溶胶 - 凝胶自燃方法合成锂镍铁素体Li0.5FE2O4。将制备的铁素体与聚苯乙烯的比例0.25:1(FP1),0.50:1(FP2),0.75:1(FP3)和1:1(FP4)与0.55:1(FP1),0.75:1(FP4)混合以获得铁氧体 - 聚苯乙烯复合材料。通过X射线衍射,电介质和直流电阻率测量来表征合成的样品。 X射线衍射图案表明聚苯乙烯本质上是无定形的。通过增加铁氧体填料含量,铁氧体 - 聚苯乙烯复合材料的衍射峰变得更清晰,更窄。室温电阻率从4.63×10(13)欧米格-CM至3.67×10(9)ω-cm,随着铁氧体含量的增加,温度依赖性电阻率随着温度的增加而降低。随着铁素体浓度的增加,介电常数增加在基础样品中。最大值为23.60的最后一个样本。相反,频率的增加导致介电常数的降低遵循Maxwell-Wagner模型。

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