A novel peroxopolyoxoniobate incorporating mixed heteroatoms: [P2Se2Nb6(O-2)(6)O-22](8-)

Yang Zongfei; Mu Qiushui; Liang Zhijie; Ma Pengtao; Niu Jingyang; Wang Jingping

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A novel peroxopolyoxoniobate incorporating mixed heteroatoms: [P2Se2Nb6(O-2)(6)O-22](8-)

机译：包含混合杂原子的新型过氧化毒毒素：[P2Se2NB6（O-2）（6）O-22]（8-）

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A novel hetero selenato-phosphato-peroxopolyoxoniobate with the formula Cs4H4[P2Se2Nb6(O-2)(6)O-22]center dot 10H(2)O has been successfully isolated in an acidified aqueous hydrogen peroxide solution. The synthesized cluster represents the first example of a selenium-containing polyoxoniobate. Furthermore, the ESI-MS spectra show that the polyoxoanion structural unit [P2Se2Nb6(O-2)(6)O-22](8-) remains intact in aqueous solution.

机译：具有式CS4H4的新型杂亚硒酸盐 - 过氧聚氧氧氧磺酸盐，其在酸化的氢过氧化氢溶液中成功地分离了中心点10H（2）O. 合成的簇代表含硒的多氧橡胶的第一实例。此外，ESI-MS光谱表明，多氧基结构单元[P2SE2NB6（O-2）（6）O-22]（8-）在水溶液中保持完整。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第35期|共4页
作者
Yang Zongfei; Mu Qiushui; Liang Zhijie; Ma Pengtao; Niu Jingyang; Wang Jingping;
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作者单位

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

Henan Univ Coll Chem &

Chem Engn Inst Mol &

Crystal Engn Henan Key Lab Polyoxometalate Chem Kaifeng 475004 Peoples R China;

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正文语种 eng
中图分类化学;无机化学;
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1. A novel peroxopolyoxoniobate incorporating mixed heteroatoms: [P2Se2Nb6(O-2)(6)O-22](8-) [J] . Yang Zongfei, Mu Qiushui, Liang Zhijie, Dalton transactions: An international journal of inorganic chemistry . 2019,第35期

机译：包含混合杂原子的新型过氧化毒毒素：[P2Se2NB6（O-2）（6）O-22]（8-）
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A novel peroxopolyoxoniobate incorporating mixed heteroatoms: [P2Se2Nb6(O-2)(6)O-22](8-)

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