Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate

摘要

Two new layered and porous-layered borates ([H(2)dap][B7O11(OH)] (1, dap = 1,2-propanediamine) and [H3O]K3.52Na3.48{Al-2[B7O13(OH)][B5O10][B3O5]}[CO3] (2)) have been solvothermally made. 1 features a 2D layer made of the [B7O13(OH)](6-) cluster, in which H(2)dap is located in the windows of the layers. The fundamental building block (FBB) [B7O13(OH)](6-) cluster in 1 represents a new type of FBB of the hepta-borate family. 2 is a novel aluminoborate with a 3D porous-layered structure formed by three types of oxoboron clusters, [B7O13(OH)](6-), [B5O10](5-) and [B3O7](5-), respectively. The strict alternation of the different oxoboron clusters and AlO4 tetrahedra leads to the abundant channel systems of the structure. 2 is the first aluminoborate (ABO) containing three types of oxoboron clusters and the first 3D porous-layered ABO with seven types of channels. UV-vis diffuse reflectance spectra reveal that both of them are wide band-gap semiconductors and have potential applications in UV regions.