Studies towards the stereoselective total synthesis of Gliomasolide A

Kare Nagaraju; Kundoor Govinda Reddy; Palakodety Radha Krishna

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Studies towards the stereoselective total synthesis of Gliomasolide A

机译：研究胶质溶解剂的立体选择性合成的研究

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The first synthetic approach towards the Gliomasolide A is described in 15 linear steps with 4% overall yield. The key steps in this approach are RCM protocol for the construction of 14-member macrolide, a Sharpless kinetic resolution, Keck and Brown's allylations for the installation of desired stereocenters. (C) 2019 Elsevier Ltd. All rights reserved.

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2019年第48期|共3页
作者
Kare Nagaraju; Kundoor Govinda Reddy; Palakodety Radha Krishna;
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作者单位

Indian Inst Chem Technol CSIR Organ Synth &

Proc Chem Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol CSIR Organ Synth &

Proc Chem Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol CSIR Organ Synth &

Proc Chem Div Hyderabad 500007 Andhra Pradesh India;

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正文语种 eng
中图分类有机化学;
关键词
Asymmetric Keck and Brown's allylations; Sharpless kinetic resolution; Cross-metathesis; Ring-closing metathesis;

机译：不对称的凯克和棕色的烯丙基;不合理的动力学分辨率;交叉复分解;闭环复分解;

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专利

1. Studies towards the stereoselective total synthesis of Gliomasolide A [J] . Kare Nagaraju, Kundoor Govinda Reddy, Palakodety Radha Krishna Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2019,第48期

机译：研究胶质溶解剂的立体选择性合成的研究
2. Studies towards the total synthesis of (+)-13-deoxytedanolide: stereoselective synthesis of C1-C9 and C9-C17 fragments [J] . Yadav Jhillu Singh, Chinnam Vijaya Vardhan, Das Saibal Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第7期

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4. Stereoselective synthesis of 2,2-substituted chromans: Towards the total synthesis of natural products. [C] . Gloria Hernandez-Torres, Mercedes Lecea, Antonio Urbano European Symposium on Organic Chemistry . 2009

机译：2,2取代染色体的立体选择性合成：朝向天然产物的总合成。
5. Chapter one: Stereoselective total synthesis of the racemic and natural enantiomer of the marine tunicate alkaloid lepadiformine. Chapter two: Studies directed towards a total synthesis of chartelline A. [D] . Sun, Cuixiang. 2005

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6. Studies toward the First Stereoselective Total Synthesis of (±)-Quinolizidine 195C and Other Transformations [O] . Shang-Shing P. Chou, Jhih-Liang Huang 2013

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Studies towards the stereoselective total synthesis of Gliomasolide A

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