NMR relaxation in semiflexible Vicsek fractals

摘要

We consider the role of local orientational mobility for the NMR relaxation of hyperbranched macromolecules modeled in form of Vicsek fractals. The spectral density J(omega), that is relevant for the NMR relaxation, is studied for labeled segments of flexible and semiflexible Vicsek fractals. We show that the semiflexibility leads to strong effects. For flexible Vicsek fractals the function omega J(omega) has a single maximum, whose position is determined by the local-scale modes and therefore independent of the location of the labeled segments. For the labeled segments of a semiflexible Vicsek fractal, we observe a broad spectral density. It is characterized by the overall relaxation of the branch that originates from the labeled segment and by the overall relaxation of the subbranches that build this branch. In this way, going from the periphery to the inner part of the macromolecule, the labeled segments display a broader spectral density. However, this effect saturates when the labeled segments get closer to the core of the hyperbranched macromolecule, so that they do not feel their remoteness from the periphery anymore. (C) 2018 Elsevier Ltd. All rights reserved.