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Preparation and Antibacterial Properties of the Core-Shell Structure SiO_2@Ag Nanoparticles

机译:核壳结构SiO_2 @ Ag纳米颗粒的制备及抗菌性能

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摘要

The core-shell structure SiO_2@Ag nanoparticles were synthesized by a facile chemical reduction method. Firstly, the mercapto-silica spheres had been prepared by the stober method, in which 3-mercaptopropyltrimethoxysilane (MPS) was used as a sole silica source. The reaction involves mixing the MPS precursor, ammonia in aqueous solvent at room temperature. Secondly, the core-shell structure SiO_2@Ag nanoparticles were synthesized by reducing AgNO_3 on the surface of mercapto-silica spheres in the presence of the reducing agent. The core-shell structure SiO_2@Ag nanoparticles were investigated by means of ultraviolet-visible absorption spectroscopy (UV-vis), high resolution transmission electron microscopy (HRTEM), X-ray powder diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Antibacterial properties of the as-synthesized SiO_2@Ag nanoparticles were investigated using both Gram negative of Escherichia coli (E.coli) and Gram positive of Staphylococcus aureus (S. aureus) as bacterial strains. The results show that the core-shell structure SiO_2@Ag nanoparticles exhibit excellent antibacterial properties against E. coli and S. aureus bacteria.
机译:采用简便的化学还原法合成了核壳结构的SiO_2 @ Ag纳米颗粒。首先,通过stober方法制备了巯基二氧化硅球,其中3-巯基丙基三甲氧基硅烷(MPS)被用作唯一的二氧化硅源。该反应涉及在室温下将MPS前体氨与氨在水性溶剂中混合。其次,通过在还原剂存在下还原巯基二氧化硅球表面的AgNO_3,合成了核壳结构SiO_2 @ Ag纳米颗粒。通过紫外可见吸收光谱法(UV-vis),高分辨率透射电子显微镜(HRTEM),X射线粉末衍射(XRD)和X射线光电子能谱(XPS)研究了SiO_2 @ Ag纳米颗粒的核壳结构。 )。以大肠杆菌(E.coli)的革兰氏阴性和金黄色葡萄球菌(S. aureus)的革兰氏阳性作为细菌菌株,研究了合成后的SiO_2 @ Ag纳米颗粒的抗菌性能。结果表明,核-壳结构SiO_2 @ Ag纳米颗粒对大肠杆菌和金黄色葡萄球菌具有优异的抗菌性能。

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