Nickel-Catalyzed Reductive Cross-Coupling of Vinyl Bromides with Unactivated Alkyl Halides

摘要

The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl-and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated a-alkenyl bromides resulted in the a-products in good results.