Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst

Kon Yoshihiro; Nakashima Takuya; Fujitani Tadahiro; Murayama Toru; Ueda Wataru

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Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst

机译：用氧化钛负载钼氧化钼醇醇醇脱水烯丙胺氧化钼氧化钼催化剂

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摘要

The dehydrative allylation from allyl alcohol with amines to generate various allyl amines by MoO3/TiO2 solid catalyst is described. The catalyst can be reused at least three times without a decrease of activity.

机译：用MOO3 / TiO 2固体催化剂将来自烯丙基醇的脱水烯丙基与胺产生各种烯丙基胺。催化剂可以在不降低活性的情况下重复使用至少三次。

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来源
《Synlett》 |2019年第3期|共6页
作者
Kon Yoshihiro; Nakashima Takuya; Fujitani Tadahiro; Murayama Toru; Ueda Wataru;
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作者单位

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem 1-1-1 Higashi Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem 1-1-1 Higashi Tsukuba Ibaraki 3058565 Japan;

Natl Inst Adv Ind Sci &

Technol Interdisciplinary Res Ctr Catalyt Chem 1-1-1 Higashi Tsukuba Ibaraki 3058565 Japan;

Hokkaido Univ Inst Catalysis N21W10 Sapporo Hokkaido 0010021 Japan;

Hokkaido Univ Inst Catalysis N21W10 Sapporo Hokkaido 0010021 Japan;

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原文格式 PDF
正文语种 eng
中图分类有机化学理论、物理有机化学;
关键词
allyl amine; molybdenum oxide catalyst; allyl alcohol; titanium oxide; dehydrative allylation;

机译：烯丙基胺;氧化钼催化剂;烯丙基醇;氧化钛;脱水烯丙基化;

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专利

1. Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst [J] . Kon Yoshihiro, Nakashima Takuya, Fujitani Tadahiro, Synlett . 2019,第3期

机译：用氧化钛负载钼氧化钼醇醇醇脱水烯丙胺氧化钼氧化钼催化剂
2. NaAlO2 supported on titanium dioxide as solid base catalyst for the carboxymethylation of allyl alcohol with DMC [J] . Ramesh Sreerangappa, Devred Francois, Debecker Damien P. Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2019,第期

机译：Naalo2负载二氧化钛作为固体碱催化剂，用于用DMC烯丙基醇的羧基甲基化
3. Mixed MgAl Oxide Supported Potassium Promoted Molybdenum Sulfide as a Selective Catalyst for Higher Alcohol Synthesis from Syngas MoS₂/K₂CO₃ on Mixed Metal Oxides for Higher Alcohol Synthesis [J] . Michael R. Morrill, Nguyen Tien Thao, Pradeep K. Agrawal, Catalysis Letters . 2012,第7期

机译：混合MgAl氧化物负载的钾促进的硫化钼作为在混合金属氧化物上由合成气MoS _{2 / K _{2 CO _{3 合成高级醇的选择性催化剂用于高级醇合成}}}
4. Group 5 (V, Nb and Ta) element-alkoxides as catalysts in the trans-esterification of ethylene-carbonate with methanol, ethanol and allyl alcohol [C] . International Conference on Carbon Dioxide Utilization . 2004

机译：第5组（V，Nb和Ta）元素 - 醇盐作为乙烯 - 碳酸酯与甲醇，乙醇和烯丙基醇的乙烯 - 碳酸酯的催化剂
5. Titanium(IV) oxide photocatalysts with palladium and surface acidity and photocatalytic activity of titanium(IV) oxide, tungsten(VI) oxide/titanium(IV) oxide, and molybdenum(VI) oxide/titanium(IV) oxide photocatalysts. [D] . Papp, Jennifer Ellen. 1994

机译：具有钯，表面酸度和氧化钛（IV），氧化钨（VI）/氧化钛（IV）和氧化钼（VI）/氧化钛（IV）的表面酸性和光催化活性的氧化钛（IV）光催化剂。
6. Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische -1

机译：使用乙酸烯丙酯作为烯丙基金属替代物从醇或醛氧化水平对映选择性铱催化的羰基烯丙基化
7. Efficient Chemoselective Reduction of N ‐Oxides and Sulfoxides Using a Carbon‐Supported Molybdenum‐Dioxo Catalyst and Alcohol [O] . Jiaqi Li, Shengsi Liu, Tracy L. Lohr, 2019

机译：使用碳负载钼 - DIOxO催化剂和醇的高效化学选择性降低N-氧化氮和亚砜
8. Characterization of silica-doped hydrous titanium oxide (HTO:Si)-supported nickel molybdenum (NiMo) catalyst coatings [R] . Gardner, T J, McLaughlin, LI, Lott, SE, 1994

机译：二氧化硅掺杂水合氧化钛（HTO：si）负载镍钼（Nimo）催化剂涂层的表征

Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst

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