Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C-O Activation

Ghorai Debasish; Loup Joachim; Zanoni Giuseppe; Ackermann Lutz

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Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C-O Activation

机译：通过C-O活化的空气稳定的二次磷酸用于镍催化的芳基醚的交叉偶联

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摘要

Air- and moisture-stable secondary phosphine oxides (SPOs) enabled nickel-catalyzed Kumada-Corriu cross-couplings of various arylmethyl ethers at room temperature by challenging C-O activation.

机译：通过攻击C-O活化，在室温下使空气和水分稳定的二次磷酸（SPOS）使各种芳基甲基醚的镍催化的Kumada-Corriu交叉偶联。

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来源
《Synlett》 |2019年第4期|共4页
作者
Ghorai Debasish; Loup Joachim; Zanoni Giuseppe; Ackermann Lutz;
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作者单位

Georg August Univ Inst Organ &

Biomol Chem Tammannstr 2 D-37077 Gottingen Germany;

Georg August Univ Inst Organ &

Biomol Chem Tammannstr 2 D-37077 Gottingen Germany;

Univ Pavia Dept Chem Viale Taramelli 10 I-27100 Pavia Italy;

Georg August Univ Inst Organ &

Biomol Chem Tammannstr 2 D-37077 Gottingen Germany;

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原文格式 PDF
正文语种 eng
中图分类有机化学理论、物理有机化学;
关键词
C-O activation; arylation; cross-coupling; secondary phosphine oxide; nickel;

机译：C-O激活;芳族;交叉耦合;二次磷化膦;镍;

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专利

1. Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C-O Activation [J] . Ghorai Debasish, Loup Joachim, Zanoni Giuseppe, Synlett . 2019,第4期

机译：通过C-O活化的空气稳定的二次磷酸用于镍催化的芳基醚的交叉偶联
2. Cross-coupling of Aryl/Alkenyl Silyl Ethers with Grignard Reagents through Nickel-catalyzed C-O Bond Activation [J] . Fei Zhao, Da-Gang Yu, Ru-Yi Zhu Chemistry Letters . 2011,第9期

机译：通过镍催化的C-O键活化，芳基/烯基甲硅烷基醚与格氏试剂的交叉偶联
3. Air-stable phosphine sulfide ligand precursors for nickel-catalyzed cross-coupling reactions of unactivated aryl chlorides with aryl grignard reagents [J] . Li GY., Marshall WJ. Organometallics . 2002,第4期

机译：空气稳定的硫化膦配体前体，用于未活化的芳基氯化物与芳基格氏试剂的镍催化交叉偶联反应
4. Nickel-Catalyzed Cross-Coupling Reaction of Anisole Derivatives with Organoboron Compounds via C-O Bond Cleavage [C] . Mamoru Tobisu, Toshiaki Shimasaki, Naoto Chatani Symposium on Organometallic Chemistry . 2008

机译：通过C-O键裂解镍催化偶氧衍生物与有机硼化合物的交叉偶联反应
5. Nickel-Catalyzed Cross-Coupling Reactions Through C-O and C-N Bond Activation [D] . ?Hoerrner, Megan E. 2020

机译：镍催化的交叉偶联通过 C-O 和 C- N键活化反应
6. Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides [O] . Nolan T. McDougal, Jan Streuff, Herschel Mukherjee, -1

机译：缺电子叔BupHOX的快速合成配体：芳基溴与仲膦氧化物交叉耦合
7. Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C–O Activation [O] . Debasish Ghorai, Joachim Loup, Giuseppe Zanoni, 2019

机译：通过C-O活化的空气稳定的二次磷酸用于镍催化的芳基醚的交叉偶联

Air-Stable Secondary Phosphine Oxides for Nickel-Catalyzed Cross-Couplings of Aryl Ethers by C-O Activation

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