Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2':6',2'-Terpyridin-4'-y1 Units at the Periphery

Thomas Bauer; A. Dieter Schluter; Junji Sakamoto

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Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2':6',2'-Terpyridin-4'-y1 Units at the Periphery

机译：朝向2D和3D配位聚合物：在周边的2,2'：6'，2英寸 - 吡啶-4'-Y1单元合成形状持久的星形单体

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摘要

A set of shape-persistent star-shaped monomers which are multiply equipped with 2,2':6',2"-terpyridin-4'-yl units has been synthesized. The synthetic sequences rest upon the Suzuki-Miyaura cross-coupling reaction which includes a sterically challenging sixfold coupling of a bulky aryl boronate to hexabromobenzene.

机译：已经合成了一组形状持续的星形单体，其配备2,2'：6'，2英寸 - 吡啶-4'-YL单元。合成序列依赖于铃木 - 宫系交叉偶联反应其中包括将稀芳基硼酸盐与六溴苯的三倍挑战六倍偶联。

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来源
《Synlett 》 |2010年第6期| 共4页
作者
Thomas Bauer; A. Dieter Schluter; Junji Sakamoto;
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作者单位

Laboratory of Polymer Chemistry Institute of Polymers Department of Materials ETH Zurich Wolfgang-Pauli-Str. 10 HCI G523 8093 Zurich Switzerland;

Laboratory of Polymer Chemistry Institute of Polymers Department of Materials ETH Zurich Wolfgang-Pauli-Str. 10 HCI G523 8093 Zurich Switzerland;

Laboratory of Polymer Chemistry Institute of Polymers Department of Materials ETH Zurich Wolfgang-Pauli-Str. 10 HCI G523 8093 Zurich Switzerland;

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原文格式 PDF
正文语种 eng
中图分类有机化学理论、物理有机化学 ;
关键词
palladium; steric hindrance; chelates;

机译：钯;空间障碍;螯合物;

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1. Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2':6',2"-Terpyridin-4'-y1 Units at the Periphery [J] . Thomas Bauer, A. Dieter Schluter, Junji Sakamoto Synlett . 2010 ,第6期

机译：朝向2D和3D配位聚合物：在周边的2,2'：6'，2英寸 - 吡啶-4'-Y1单元合成形状持久的星形单体
2. A New Family of 2D Coordination Polymers Based on 3d‐4f 15‐Metallacrown‐5 Units: Synthesis, Structure, and Single‐Molecule Magnet Behavior [J] . Zhang Hong‐Gang, Yang Hua, Sun Lei, European journal of inorganic chemistry . 2019 ,第23期

机译：基于3D-4F 15-Metallacrown-5单元的新的2D协调聚合物系列：合成，结构和单分子磁体行为
3. Synthesis, structure and photoluminescence of a 3D pillared heterometallic coordination polymer containing 2D inorganic cadmium-potassium-oxide layer subunits [J] . Liu QY, Wang YL, Liu JH Crystal Research and Technology: Journal of Experimental and Industrial Crystallography . 2009 ,第3期

机译：包含2D无机镉-钾-氧化物层亚单元的3D柱状异金属配位聚合物的合成，结构和光致发光
4. Synthesis of metal-centered star-shaped polymer by coordination of 2,2'-bipyridyl-terminated organic polymer with transition metal ion [C] . G.Konishi, K.Naka, Y.Chujo Pacific polymer conference preprints . 1999

机译：用2,2'-双吡啶封端的有机聚合物与过渡金属离子的合成金属居中星形聚合物
5. Synthesis of functional polymers with controlled architecture by ATRP of monomers in the presence of cross-linkers: From stars to gels [D] . Gao, Haifeng 2008

机译：在交联剂存在下，通过单体的ATRP合成具有受控结构的功能聚合物：从星形到凝胶
6. Coordination Polymer: Synthesis Spectral Characterization and Thermal Behaviour of Starch-Urea Based Biodegradable Polymer and Its Polymer Metal Complexes [O] . Ashraf Malik, Shadma Parveen, Tansir Ahamad, 2010

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7. Synthesis of 5-substituted 1,3-bis(2,2′:6′,2″-terpyridin-4′-ylethynyl)benzene ligands and their coordination-driven self-assembly [O] . Seok-Ho Hwang, Charles N. Moorefield, Hee-Chul Cha, 2006

机译：合成5-取代的1,3- 双（2,2'：6'，2“ - 吡啶-4'-氯乙炔基）”苯配体及其协调驱动的自组装
8. Cyclobutene-Containing Monomers and Polymers. Polymerization and Crosslinking via Thermally Generated Butadiene Units [R] . Mathias, L. J., Powell, D. G. 1987

机译：含有环丁烯的单体和聚合物。通过热生成丁二烯单元的聚合和交联

Towards 2D and 3D Coordination Polymers: Synthesis of Shape-Persistent Star Monomers with 2,2':6',2'-Terpyridin-4'-y1 Units at the Periphery

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