A highly sensitive and selective bis(salamo)-type fluorescent chemosensor for identification of Cu2+ and the continuous recognition of S2-, Arginine and Lysine

摘要

A novel bis(salamo)-type chemosensor H3L was synthesized and characterized. It was found that the sensor molecule can selectively recognize Cu2+, and its L-Cu2+ is highly sensitive to the detection of S2- anion, Arginine and Lysine when dissolved in ethanol solvent. The sensor H3L can be used to identify a relay sensor for Cu2+, while the L-Cu2+ recognizes S2- anion, Arginine and Lysine with high selectivity and sensitivity over an acceptable physiological pH range. The detection line of the sensor molecule H3L is 1.02 x 10(-6) M, and its binding constant to Cu2+ is 1.54 x 10(6) M-1. The detection line of L-Cu2+ as a sensor is calculated as 5.57 x 10(-7) M, and its binding constants with S-2- anion, Arginine and Lysine are 2.80 x 10(5) M-1, 5.32 x 10(6) M-1 and 5.94 x 10(6) M-1, respectively. The crystal structure of the Cu(II) complex [Cu-4(L)(2)(CH3OH)(2)].2NO(3) with the sensor molecule H3L has been determined by single crystal X-ray crystallography. (C) 2019 Elsevier B.V. All rights reserved.