Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates

Modi Anju; Ali Wajid; Patel Bhisma K.

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Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates

机译：使用Aroyl异硫氰酸酯的有机催化区域伴随着硫氰化合物和氧化氧化的酰化

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A regioselective and concomitant transfer of thiocyanate (-SCN) and aroyl/acyl (-COR) groups from aroyl/acyl isothiocyanates onto oxiranes was achieved, giving thiocyanato benzoates in 100% atom economy. In this biomimetic organocatalytic process, one part (-SCN) of aroyl/acyl isothiocyanates acts as the nucleophile whereas the other half (-COR) serves as an electrophilic partner.

机译：从Aryol /酰基异硫氰酸酯到香草中的硫代氰酸酯（-SCN）和芳酰/酰基（-COR）基团的区域选择性和伴随转移，得到硫氰酸噻唑酸盐在100％原子经济中。在该仿生有机催化过程中，芳酰基/酰基异硫氰酸酯的一部分（-SCN）用作核官，而另一半（ - COR）用作电子亲色伴侣。

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《Organic letters》 |2017年第3期|共4页
作者
Modi Anju; Ali Wajid; Patel Bhisma K.;
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Indian Inst Technol Guwahati Dept Chem North Guwahati 781039 India;

Indian Inst Technol Guwahati Dept Chem North Guwahati 781039 India;

Indian Inst Technol Guwahati Dept Chem North Guwahati 781039 India;

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正文语种 eng
中图分类有机化学;
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1. Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates [J] . Modi Anju, Ali Wajid, Patel Bhisma K. Organic letters . 2017,第3期

机译：使用Aroyl异硫氰酸酯的有机催化区域伴随着硫氰化合物和氧化氧化的酰化
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Organocatalytic Regioselective Concomitant Thiocyanation and Acylation of Oxiranes Using Aroyl Isothiocyanates

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