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Pepluanols C–D, Two Diterpenoids with Two Skeletons from Euphorbia peplus

机译：Pepluanols c-d，两种二萜类含有来自大戟Peples的两种骨架

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摘要

Pepluanols C and D (1 and 2 ), featuring unprecedented 5/5/10 with out,out -[7.2.1]bicylcododecane core and 6/6/7/3 fused-ring skeletons, respectively, were isolated from Euphorbia peplus . Their chemical structures and absolute configurations were determined by a series of extensive spectroscopic methods, and X-ray diffraction analysis. In addition, pepluanols C and D showed 31.6 ± 8.3% and 30.5 ± 2.8% peak current inhibition on the K_(v)1.3 potassium channel at 30 μM.
机译：Pepluanols c和d（ 1和 2），具有前所未有的5/5/10，其中 out，Out - [7.2.1]双癸烷核心和6/6/7/3融合环骨架 分别从大戟培养物中分离出来。 它们的化学结构和绝对构型由一系列广泛的光谱方法和X射线衍射分析确定。 此外，Pepluanols C和D在30μm的K_（v）1.3钾通道上显示31.6±8.3％和30.5±2.8％峰值电流抑制。

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  • 来源
    《Organic letters》 |2018年第10期|共5页
  • 作者

    Luo-Sheng Wan; Yin Nian; Xing-Rong Peng; Li-Dong Shao; Xiao-Nian Li; Jian Yang; Ming Zhou; Ming-Hua Qiu;

  • 作者单位

    State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650201 P. R. China;

    Key Laboratory of Animal Models and Human Diease Mechanisms and Ion Channel Research and Drug Development Center Kunming Institute of Zoology Chinese Academy of Sciences Kunming 650223 P. R. China;

    State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650201 P. R. China;

    State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650201 P. R. China;

    State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650201 P. R. China;

    Key Laboratory of Animal Models and Human Diease Mechanisms and Ion Channel Research and Drug Development Center Kunming Institute of Zoology Chinese Academy of Sciences Kunming 650223 P. R. China;

    Key Laboratory of Animal Models and Human Diease Mechanisms and Ion Channel Research and Drug Development Center Kunming Institute of Zoology Chinese Academy of Sciences Kunming 650223 P. R. China;

    State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650201 P. R. China;

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  • 正文语种 eng
  • 中图分类 有机化学;
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