A turn-on fluorescent probe for Cd2+ detection in aqueous environments based on an imine functionalized nanoscale metal-organic framework

摘要

A novel fluorescent probe was synthesized and explored to detect cadmium ions (Cd2+) based on an imine functionalized metal-organic framework (MOF). The nanoscale MOF probe (similar to 100 nm) displayed a turn-on fluorescence in aqueous environments with the addition of Cd2+ which could be ascribed to the interaction between the C=N group and specific metal ions, presenting a low-toxicity, highly selective and sensitive detection method for Cd2+ with a detection limit of 0.336 mu M (37.8 ppb) and a broad linear range of 0-500 mM, which is promising for application in intracellular sensing and imaging of Cd2+. The probing mechanism was studied and discussed in detail.