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Synthesis of porous carbon via a waste tire leavening strategy for adsorptive desulfurization

机译:通过废气脱硫策略对多孔碳的合成,用于吸附脱硫

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摘要

Adsorptive desulfurization is an effective technology for removing harmful sulfur under mild conditions. Carbon materials have many advantages and are often used in adsorption desulfurization research, but until now have been synthesized using complicated methods and have shown limited adsorption capacity. Using an NaHCO3-assisted leavening method, waste tires were in the current work used as raw materials to produce hierarchically porous carbon that exhibits a high specific surface area and abundant oxygen-containing functional groups. In contrast to the sulfur removal by the carbon material prepared using a commonly used method, the as-prepared carbon material shows excellent adsorption performance, and was able to achieve an ultra-deep desulfurization of pentanethiol, specifically removing up to 99.7% of the sulfur from a model fuel with an initial sulfur concentration of 28 ppm. Therefore, we have provided a simple method for synthesizing adsorbents with high adsorption performance, and we expect these adsorbents to be used for industrial adsorptive desulfurization.
机译:吸附脱硫是在温和条件下除去有害硫的有效技术。碳材料具有许多优点,并且通常用于吸附脱硫研究,但直到现在已经使用复杂的方法合成并显示了有限的吸附能力。使用NaHCO3辅助的升温方法,废轮胎在当前的工作中用作原料以产生具有高比表面积和丰富的含氧官能团的分层多孔碳。与使用常用方法制备的碳材料的硫去除相反,制备的碳材料具有优异的吸附性能,并且能够实现戊硫醇的超深脱硫,特别地除去高达99.7%的硫从模型燃料,初始硫浓度为28ppm。因此,我们提供了一种简单的方法,用于合成具有高吸附性能的吸附剂,我们预计这些吸附剂可用于工业吸附性脱硫。

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    《RSC Advances》 |2019年第52期|共6页
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  • 正文语种 eng
  • 中图分类 化学;
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