Four 3D coordination polymers based on layers with single syn-anti carboxylate bridges: synthesis, structures, and magnetic properties

摘要

Four novel coordination polymers (CPs) based on a new 4-(3,5-dicarboxylphenyl) picolinic acid ligands (H3L), [M-3(L)(2)(H2O)(6)]4H(2)O (M-3 = Mn-3, 1; Co-3, 2; Ni-3, 3, Co1.01Ni1.99, 4), have been hydrothermally synthesized, and structurally and magnetically characterized. In these isomorphous CPs, octahedrally coordinated metal ions are linked by the single syn-anti carboxylate bridge (-COO) to give linear trinuclear motifs. The motifs are connected through the other single syn-anti carboxylate bridge (-COO) to give a 2D (4,4) layer, and the layers are interlinked by the L ligands into 3D frameworks. Magnetic measurement indicates that antiferromagnetic interactions between metal ions are mediated through the single syn-anti carboxylate bridges in 1 and 2, while the same carboxylate bridges in 3 transmit ferromagnetic couplings. The bimetallic CP 4 shows interesting complicated magnetic behaviors due to the competition effect of Co(ii) and Ni(ii) ions.