A Halogen-Free Green High Energy Density Oxidizer from H-FOX

摘要

Reaction of H-FOX (1-hydrazinyl-2,2-dinitroethenamine) with 2,2,2-trinitroethanol resulted in an unexpected compound, 1,1'-methylenebis[3-(2,2,2-trinitroethyl)urea] (5), which when treated with acetic anhydride and 100 % nitric acid gave an N-NO_2 derivative, 1,1'-methylenebis[1-nitro-3-(2,2,2-tri-nitroethyl)urea] (6) in good yield. Compound 6 exhibits a good oxygen balance (+20.4 %), density (d = 1.87 g/cm~3) and excellent detonation performance (vD = 8910 m/s; P = 35.8 GPa) as well as acceptable stability and sensitivity, which suggests it as an attractive replacement for ammonium perchlorate (AP).