Palladium‐Catalyzed Domino Reaction of Two Aryl Iodides involving C–H Activation Processes: Efficient Synthesis of Fused Polycycles

He Hai‐Yu; Wang Wei; Yu Xiao‐Jun; Huang Jin; Jian Lei; Fu Hai‐Yan; Zheng Xue‐Li; Chen Hua; Li Rui‐Xiang

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Palladium‐Catalyzed Domino Reaction of Two Aryl Iodides involving C–H Activation Processes: Efficient Synthesis of Fused Polycycles

机译：钯催化的两种芳碘化物的多米诺反应涉及C-H活化过程：有效合成融合多环

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摘要

> The palladium‐catalyzed domino intermolecular C(sp 2 )–H activation reaction of two aryl iodides was explored. This simple palladium catalytic system showed good activity.

机译： >钯催化的多米诺分子分子c（sp 2 ）-h活化反应探索了两个芳基碘。这种简单的钯催化系统显示出良好的活性。

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来源
《European journal of organic chemistry》 |2016年第34期|共4页
作者
He Hai‐Yu; Wang Wei; Yu Xiao‐Jun; Huang Jin; Jian Lei; Fu Hai‐Yan; Zheng Xue‐Li; Chen Hua; Li Rui‐Xiang;
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作者单位

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

State Key Laboratory of Biotherapy and Cancer CenterSichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

Key Laboratory of Green Chemistry and TechnologySichuan University610064 Chengdu China;

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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
C–H activation; Carbopalladation; Domino reactions; Fused‐ring systems; Palladium; Polycycles;

机译：C-H激活;碳结渣;多米诺反应;融合环系统;钯;多环;

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专利

1. Palladium‐Catalyzed Domino Reaction of Two Aryl Iodides involving C–H Activation Processes: Efficient Synthesis of Fused Polycycles [J] . He Hai‐Yu, Wang Wei, Yu Xiao‐Jun, European journal of organic chemistry . 2016,第34期

机译：钯催化的两种芳碘化物的多米诺反应涉及C-H活化过程：有效合成融合多环
2. Palladium-Catalyzed Tandem Reaction of Three Aryl Iodides Involving Triple C–H Activation [J] . Xiai Luo, Yankun Xu, Genhua Xiao, Organic letters . 2018,第10期

机译：三个芳碘化物的钯催化串联反应涉及三重C-H激活
3. Understanding sulfone behavior in palladium-catalyzed domino reactions with aryl iodides [J] . Alonso I, Alcami M, Mauleon P, Chemistry: A European journal . 2006,第17期

机译：了解砜与芳基碘化物在多米诺骨牌反应中的砜行为
4. On the Mechanism of Aryl Halide Activation in Nickel- and Palladium-Catalyzed Cross-Coupling Reactions [C] . Naohiko Yoshikai, Hirokazu Matsuda, Eiichi Nakamura Symposium on Organometallic Chemistry . 2007

机译：镍和钯催化交叉偶联反应中芳基卤化物活化机理
5. Directed ortho metalation and palladium-catalyzed aryl-aryl cross-coupling reactions. Synthesis of heteroaromatics and alkaloids. [D] . Siddiqui, Mohammad Arshad. 1990

机译：定向原位金属化和钯催化的芳基-芳基交叉偶联反应。杂芳族化合物和生物碱的合成。
6. Two Palladium-Catalyzed Domino Reactions from One Set of Substrates/Reagents: Efficient Synthesis of Substituted Indenes and cis-Stilbenoid Hydrocarbons from the Same Internal Alkynes and Hindered Grignard Reagents [O] . Cheng-Guo Dong, Pik Yeung, Qiao-Sheng Hu -1

机译：从一组底物/试剂中进行两个钯催化的多米诺反应：从相同的内部炔烃和受阻的格氏试剂中高效合成取代的茚类和顺式-类苯乙烯烃
7. Pd-Catalyzed Alkyl to Aryl Migration and Cyclization: An Efficient Synthesis of Fused Polycycles via Multiple C-H Activation [O] . -1

机译：PD-催化的烷基至芳基迁移和环化：通过多个C-H激活有效合成熔融多环素

Palladium‐Catalyzed Domino Reaction of Two Aryl Iodides involving C–H Activation Processes: Efficient Synthesis of Fused Polycycles

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