Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model

Hanauer Kristina; F?rster Christoph; Heinze Katja

摘要

Abstract >Invited for the cover of this issue is the group of Katja Heinze from Johannes Gutenberg University of Mainz, Germany. The cover image shows two key steps of the oxygenation of phosphanes employing bioinspired molybdenum(VI) – ferrocenium heterometallic complexes: oxygen atom transfer from the dioxido molybdenum(VI) moiety to the substrate is followed by an intramolecular electron transfer from the molybdenum(IV) to the ferrocenium site. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”> <title类型=“main”>邀请的封面邀请了这个问题的抽象</ title> >是来自德国华美州大学Johannes Gutenberg大学的Katja Heinze集团。封面图像显示使用生物悬浮钼（VI） - 亚铁核杂交络合物的磷酸氧化氧合的两个关键步骤：从二氧化钼钼（VI）部分与基材的氧原子转移，然后是来自钼（IV）的分子内电子转移到铁源位点。</ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-23007/'>《European journal of inorganic chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第31期</span><b style="margin: 0 2px;">|</b><span>共1页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hanauer Kristina&option=202" target="_blank" rel="nofollow">Hanauer Kristina;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=F?rster Christoph&option=202" target="_blank" rel="nofollow">F?rster Christoph;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heinze Katja&option=202" target="_blank" rel="nofollow">Heinze Katja;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10‐14 55128 Mainz Germany;</p> <p>Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10‐14 55128 Mainz Germany;</p> <p>Institute of Inorganic Chemistry and Analytical ChemistryJohannes Gutenberg University of MainzDuesbergweg 10‐14 55128 Mainz Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1183.html" title="无机化学">无机化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> </p> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019828075.html">Front Cover: Redox‐Controlled Stabilization of an Open‐Shell Intermediate in a Bioinspired Enzyme Model (Eur. 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rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 毛彦俊</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201726865.html">新的土壤微生物、从所述土壤微生物分离的新氧化还原酶、编码所述氧化还原酶的基因和使用所述微生物、氧化还原酶和基因产生糖苷配基的方法</a> <b>[P]</b> . <span> 中国专利： CN103237884B </span> <span> . 2015.08.19</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101925468.html">新的土壤微生物、从所述土壤微生物分离的新氧化还原酶、编码所述氧化还原酶的基因和使用所述微生物、氧化还原酶和基因产生糖苷配基的方法</a> <b>[P]</b> . <span> 中国专利： CN103237884A </span> <span> . 2013-08-07</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130454414428.html">Detergent composition containing liquid stabilized enzyme detergent composition containing aqueous stabilized enzyme detergent composition containing stabilized solid block enzyme detergent composition containing stabilized enzyme particulate liquid with stabilized enzyme and method of cleaning and sanitizing a processing unit for a food product containing protein</a> <b>[P]</b> . <span> 外国专利：  BR9508880A </span> <span> . 1997-12-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含有液体稳定酶洗涤剂组合物的洗涤剂组合物，含有含水稳定酶洗涤剂组合物的洗涤剂组合物，含有稳定酶颗粒液体和稳定酶的稳定固体块状酶洗涤剂组合物，以及清洁和消毒含有蛋白质的食品的处理单元的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130443714885.html">Core-shell particle production from inorganic, e.g. titanium oxide, nanoscalar cores for use e.g. as biocidal particles or pigments for water treatment involves wet chemical method, especially using enzyme or redox reaction</a> <b>[P]</b> . <span> 外国专利：  DE10131173A1 </span> <span> . 2003-01-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由无机物例如氧化钛，纳米标量芯，例如因为用于水处理的杀菌颗粒或颜料涉及湿化学方法，尤其是使用酶或氧化还原反应 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130462968473.html">blood. Redox enzyme systems obtainable from chrysogenium, sets of genes encoding them and their use for high antibiotic production of redox enzymes or genes encoding them</a> <b>[P]</b> . <span> 外国专利：  KR920702419A </span> <span> . 1992-09-04</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：血液。可从金相细菌获得的氧化还原酶系统，编码它们的基因集及其在高抗生素生产氧化还原酶或编码它们的基因中的用途 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704019827802','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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