LaCoO3-delta coated Ba0.5Sr0.5Co0.8Fe0.2O3-delta cathode for intermediate temperature solid oxide fuel cells

摘要

Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) is a promising cathode for intermediate temperature solid oxide fuel cells. However, BSCF cathode performance stability has been a challenge and its electrochemical performance deteriorates severely in the presence of Cr2O3-forming metallic interconnect. We demonstrate that LaCoO3-delta (LC) coating on BSCF cathode can not only enhance BSCF electrochemical performance, but also effectively improve the BSCF performance stability. In this study, LC-coated BSCF-Gd0.1Ce0.9O1.9 (LC@BSCF-GDC) cathode is prepared through a solution impregnation method and systematically characterized. EIS, XRD, Raman, SEM and EDS tests with and without SUS430 interconnect are conducted to characterize the Cr-tolerance. The results show that BSCF-GDC cathode is susceptible to Cr poisoning while LC@BSCF-GDC cathode has significantly enhanced tolerance to Cr poisoning. Single cells with LC@BSCF-GDC cathode achieve higher peak power density and smaller polarization resistance values than single cells with BSCF-GDC cathode. Furthermore, significant improvement of performance stability under a constant current load has been achieved for single cells with LC@BSCF-GDC cathode. This work provides a new solution for solving BSCF cathode performance stability. (C) 2019 Elsevier Ltd. All rights reserved.