Pentacoordinate cobalt(II) complexes with neutral tripodal <ce:italic>N</ce:italic>-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry

Salah S. Massoud; Roland C. Fischer; Franz A. Mautner; Megan M. Parfait; Radovan Herchel; Zdeněk Trávní?ek

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Pentacoordinate cobalt(II) complexes with neutral tripodal N-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry

机译：与中性三码头的五角星钴（II）复合物 n -donor配体：用于扭曲的三角形双滤网几何的零场分裂

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?Pentacoordinate Co(II) complexes with τ?=?0.7–1.0 were synthetized.

?Variation of tripodal N-donor ligands and counter-ions on anisotropy was studied.

?The correlation between |D| and τ-parameters was established.

Abstract

A series of pentacoordinate Co(II) complexes of the composition [Co(bpdmpz)Cl]ClO4(1), [Co(bpdmpz)Cl]PF6(2), [Co(bdmpzp)Cl]ClO4·H2O (3), [Co(bdmpzp)Cl]PF6(4), [Co(tdmpza)Cl]ClO4

机译：<！[CDATA [ 图形抽象显示中省略亮点 < CE：简单 - 对ID = “sp0010” 视图= “所有”> 五配位钴（II）配合物与τ= 0.7-1.0进行synthetized ？

三足的N-供体配体和反荷离子对各向异性的变化得s tudied <？CE：对ID = “P0015” 视图= “所有”>的之间的相关性| d |并建立τ-参数 < CE：抽象的xmlns：CE = “http://www.elsevier.com/xml/common/dtd” 的xmlns = “http://www.elsevier.com/xml/ja/dtd” 级= “作者” 的xml：郎= “EN” ID = “AB015” 视图= “所有”> 抽象一系列组合物的五配位钴（II）配合物的[CO（bpdmpz）CL] CLO 4 （ 1 ），[CO（bpdmpz）CL] PF 6 （< CE：粗体> 2 ），[CO（bdmpzp）CL] CLO 4 ·H 2 O（ 3 ），[CO（bdmpzp）CL] PF 6 （< CE：粗体> 4 ），[CO（tdmpza）CL] CLO 4

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《Inorganica Chimica Acta》 |2018年第2018期|共10页
作者
Salah S. Massoud; Roland C. Fischer; Franz A. Mautner; Megan M. Parfait; Radovan Herchel; Zdeněk Trávní?ek;
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作者单位

Department of Chemistry University of Louisiana at Lafayette;

Institut für Anorganische Chemische Technische Universit?t Graz;

Institut für Physikalische and Theoretische Chemie Technische Universit?t Graz;

Department of Chemistry University of Louisiana at Lafayette;

Department of Inorganic Chemistry Faculty of Science Palacky University;

Department of Inorganic Chemistry Faculty of Science Palacky University;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Cobalt(II) complexes; Tripodal ligands; Crystal structure; Magnetic properties; Single-molecule magnets;

机译：钴（ii）复合物;三翼式配体;晶体结构;磁性;单分子磁铁;

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1. Pentacoordinate cobalt(II) complexes with neutral tripodal N-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry [J] . Salah S. Massoud, Roland C. Fischer, Franz A. Mautner, Inorganica Chimica Acta . 2018,第期

机译：与中性三码头的五角星钴（II）复合物 n -donor配体：用于扭曲的三角形双滤网几何的零场分裂
2. Electron structure of organometal complexes of f-elements. 56. Parametric analysis of crystal field splitting patterns of pseudo-trigonal-bipyramidal coordinated O-donor and P-donor functionalized ethylcylopentadienyl complexes of neodymium(III) [Ger [J] . Amberger HD., Reddmann H., Karsch HH., Journal of Organometallic Chemistry . 2003,第1a2期

机译：f元素的有机金属配合物的电子结构。 56.伪三角-双锥体配位的钕（III）的O-供体和P-供体官能化的乙基环戊二烯基配合物的晶体场分裂模式的参数分析[Ger
3. Synthesis and characterization of copper(II) complexes containing acetate and N, N-donor ligands, and their electrochemical behavior in dopamine detection [J] . Andrea P. Sandoval-Rojas, Laura Ibarra, María Teresa Cortés, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2017,第期

机译：含有乙酸酯和斜体> N ， n ，，，
4. Field-induced Slow Magnetic Relaxation in Tetrahedral Cobalt(II)Complexes with Halide Donors [C] . RyojiMitsuhashi, Satoshi Hosoya, Takayoshi Suzuki 日本化学会春季年会 . 2020

机译：用卤化物供体在四面体钴（II）配合物中诱导的慢磁性松弛
5. Stereoisomers of Cobalt(III) Complexes with the Bi-or Tridentate Ligands Containing a Thioether Donor Atom [D] . Yamanari, Kazuaki -1

机译：钴（III）配合物与含硫醚供体原子的双齿或三齿配体的立体异构体
6. Terminal NiII−OH/−OH2 complexes in trigonal bipyramidal geometries derived from H2O [O] . Nathanael Lau, Yohei Sano, Joseph W. Ziller, -1

机译：来自H2O的三角双锥体几何中的末端NiII-OH / -OH2络合物
7. Structural, Magnetic, and Spectroscopic Characterization of the Pyridine Complexes of Copper(II) Triphenylacetate: A Dimeric Copper(II) Triphenylacetate–Pyridine Complex with Distorted Trigonal Bipyramidal Geometry Around Copper [O] . Omar W. Steward, Michinobu Kato, Shih-Chi Chang, 1991

机译：铜（II）三苯基乙酸吡啶络合物的结构，磁性和光谱表征：一种二聚体铜（II）三苯基乙酸吡啶 - 吡啶络合物，铜周围扭曲的三角形双滤网几何形状

Pentacoordinate cobalt(II) complexes with neutral tripodal N-donor ligands: Zero-field splitting for a distorted trigonal bipyramidal geometry

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