Crystal structure and bio-catalytic potential of oxovanadium(IV) Schiff base complexes derived from 2-hydroxy-4-(prop-2-yn-1-yloxy)benzaldehyde and alicyclic/aromatic diamines

Chithiraivel Balakrishnan; M.A. Neelakantan

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Crystal structure and bio-catalytic potential of oxovanadium(IV) Schiff base complexes derived from 2-hydroxy-4-(prop-2-yn-1-yloxy)benzaldehyde and alicyclic/aromatic diamines

机译：衍生自2-羟基-4-（PROP-2-YN-1-基氧基）苯甲醛和脂环族/芳族二胺的氧化钒（IV）Schiff基络合物的晶体结构和生物催化潜力

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Graphical abstract

Oxovanadium(IV) complexes with bio active propargyl containing Schiff bases were synthesized and structurally characterized. Bio catalytic activity of the vanadium complexes was studied.

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Highlights

?Oxovanadium(IV) N2O2 ligation Schiff base complexes.

?Spectral and single crystal XRD analysis.

?Topological analysis of the electron density.

?Catecholase, phenoxazinone synthase and haloperoxidases potential.

Abstract

Syntheses, structures, electronic properties and bio-catalytic activities of oxovanadium(IV) complexes [VOL

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图形摘要

氧化钒（IV）含有生物活性筛基碱基的辛酸碱基的络合物和结构表征。研究了钒络合物的生物催化活性。展示省略 < CE：抽象XMLNS：CE =“http://www.elsevier.com/xml/common/dtd”xmlns =“http://www.elsevier.com/xml/ja/dtd”class =“author-fighlights” XML：lang =“en”id =“ab010”视图=“全部”> 亮点

？ oxovanadium（iv）n2O2连接席夫碱基复合物。？光谱和单晶XRD分析。

？电子的拓扑分析密度。

？儿茶酚酶，苯氧嘧啶合酶和氟氧化酶电位。 < / ce：abstract>

抽象

氧化钒（IV）配合物的合成，结构，电子性质和生物催化活性[VOL

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来源
《Inorganica Chimica Acta》 |2018年第2018期|共12页
作者
Chithiraivel Balakrishnan; M.A. Neelakantan;
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作者单位

Chemistry Research Centre National Engineering College;

Chemistry Research Centre National Engineering College;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Oxovanadium(IV) Schiff base complexes; Crystal structure; Topology analysis of electron density; Bio-catalytic potential;

机译：氧化铵（IV）席夫碱基配合物;晶体结构;电子密度的拓扑分析;生物催化潜力;

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1. Crystal structure and bio-catalytic potential of oxovanadium(IV) Schiff base complexes derived from 2-hydroxy-4-(prop-2-yn-1-yloxy)benzaldehyde and alicyclic/aromatic diamines [J] . Chithiraivel Balakrishnan, M.A. Neelakantan Inorganica Chimica Acta . 2018,第期

机译：衍生自2-羟基-4-（PROP-2-YN-1-基氧基）苯甲醛和脂环族/芳族二胺的氧化钒（IV）Schiff基络合物的晶体结构和生物催化潜力
2. Synthesis, crystal structures, DNA binding and cleavage studies of two oxovanadium(IV) complexes of 1,10-phenanthroline and Schiff bases derived from tryptophan [J] . Lin Bian - Lianzhi Li, Qingfu Zhang, Jianfang Dong Transition Metal Chemistry . 2012,第8期

机译：色氨酸衍生的1,10-菲咯啉和席夫碱的两种氧钒（IV）配合物的合成，晶体结构，DNA结合和裂解研究
3. Synthesis, crystal structures, DNA binding and cleavage studies of two oxovanadium(IV) complexes of 1,10-phenanthroline and Schiff bases derived from tryptophan [J] . Lin Bian, Lianzhi Li, Qingfu Zhang, Transition Metal Chemistry . 2012,第8期

机译：色氨酸衍生的1,10-菲咯啉和席夫碱的两种氧钒（IV）配合物的合成，晶体结构，DNA结合和裂解研究
4. Synthesis and crystal structure of an oxovanadium(IV) complex containing L-phenylalanine Schiff base and 1,10-phenanthroIine [C] . Jianfang DONG, Buqin JING, Lianzhi LI International Conference on Chemical Engineering and Advanced Materials . 2014

机译：含L-苯丙氨酸席夫碱和1,10菲素的氧化钒（IV）复合物的合成和晶体结构
5. Synthesis, characterization and biological studies of trivalent transition metal complexes with Schiff bases derived from heterocyclic b-diketones and some diamines [D] . Bhagavandas Patel, Mukeshkumar. 2012

机译：具有杂环b-二酮和一些二胺的席夫碱的三价过渡金属配合物的合成，表征和生物学研究
6. Synthesis and In Vitro Antitumor Activity of Two Mixed-Ligand Oxovanadium(IV) Complexes of Schiff Base and Phenanthroline [O] . Yongli Zhang, Xiangsheng Wang, Wei Fang, 2013

机译：席夫碱和菲咯啉的两种混合配体氧钒（IV）配合物的合成及体外抗肿瘤活性
7. Oxovanadium(IV) complexes of medicinal relevance: Synthesis, characterization, and 3D-molecular modeling and analysis of some oxovanadium(IV) complexes in O,N-donor coordination matrix of sulfa drug Schiff bases derived from a 2-pyrazolin-5-one derivative [O] . R.C. Maurya, D. Sutradhar, M.H. Martin, 2015

机译：药用相关的氧钒（IV）配合物：衍生自2-吡唑啉-5-酮的磺胺类schiff碱的O，N-供体配位基质中的一些氧钒（IV）配合物的合成，表征和3D-分子模拟和分析衍生物
8. Aromatic diamine-aromatic dialdehyde high molecular weight Schiff base polymers prepared in a monofunctional Schiff base Patent [R] . Dalelio, G. F. 1970

机译：在单官能席夫碱中制备的芳族二胺 - 芳族二醛高分子量席夫碱聚合物

Crystal structure and bio-catalytic potential of oxovanadium(IV) Schiff base complexes derived from 2-hydroxy-4-(prop-2-yn-1-yloxy)benzaldehyde and alicyclic/aromatic diamines

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