Structures and magnetic properties of two series of phenoxo-O bridged Ln <ce:inf loc='post'>2</ce:inf> compounds: Two Gd <ce:inf loc='post'>2</ce:inf> compounds displaying magnetic refrigeration properties

Zhao-Peng Yu; Jie Liu; Xue Feng; Kun Zhou; Wen-Min Wang; Ying Shi

首页> 外文期刊>Inorganica Chimica Acta >Structures and magnetic properties of two series of phenoxo-O bridged Ln 2 compounds: Two Gd 2 compounds displaying magnetic refrigeration properties

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Structures and magnetic properties of two series of phenoxo-O bridged Ln 2 compounds: Two Gd 2 compounds displaying magnetic refrigeration properties

机译：两种系列酚桥的结构和磁性桥接Ln 2 化合物：两个gd 2 展示磁性制冷性能的化合物

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Graphical abstract

Compounds1and4display cryogenic magnetic refrigeration properties with maximum ?ΔSmvalues of 16.41 (1) and 18.32 (4) JK?1kg?1at 2.0K and 7.0T.

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Highlights

?Five lanthanide dinuclear compounds have been synthesized and characterized.

?The five lanthanide compounds are phenoxo-O-bridged binuclear complexes and each eight-coordinated center Ln(III) ion is in a slightly distorted dodecahedral geometry.

?1and4showed cryogenic magnetic refrigeration properties with maximum ?ΔSmvalues of 16.41 and 18.32JK?1kg?1at 2.0K and 7.0T, respectively.

机译：<！[cdata [

图形摘要

化合物 1 和 4 显示低温磁制冷特性，最大值？Δ s m 值为16.41（ 1 ）和18.32（ 4 ）jk ？1 kg 1 在2.0K和7.0T 显示中省略

突出显示 < CE：Abstract-SEC ID =“AS010”View =“全部”>

？五种镧系元素二核化合物已被合成并表征。

？五个镧系元素是苯氧烷化合物是苯氧烷-O-桥接的双核复合物和每个八个协调中心LN（III ）离子处于略带扭曲的十二次的几何形状。

？ 1 和 4 显示低温磁性制冷性能，最大？Δ s m 值为16.41和18.32jk ？1 kg ？1 分别为2.0k和7.0t。

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来源
《Inorganica Chimica Acta》 |2018年第2018期|共6页
作者
Zhao-Peng Yu; Jie Liu; Xue Feng; Kun Zhou; Wen-Min Wang; Ying Shi;
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作者单位

School of Chemistry and Chemical Engineering Linyi University;

School of Chemistry and Chemical Engineering Linyi University;

Department of Chemistry Taiyuan Normal University;

Department of Chemistry Taiyuan Normal University;

Department of Chemistry Taiyuan Normal University;

Department of Biology Taiyuan Normal University;

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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Lanthanide dinuclear complexes; Structures; Magnetic properties; Magnetic refrigeration properties;

机译：镧系金镧是金核配合物;结构;磁性;磁性制冷特性;

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Structures and magnetic properties of two series of phenoxo-O bridged Ln 2 compounds: Two Gd 2 compounds displaying magnetic refrigeration properties

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