<![CDATA[Metal ion size and the pyramidalization of trimetallic nitride units inside a fullerene cage: Comparisons of the crystal structures of M <ce:inf loc='post'>3</ce:inf>N@ <ce:italic>I <ce:inf loc='post'>h</ce:inf> </ce:italic>-C <ce:inf loc='post'>80</ce:inf> (M=Gd, Tb, Dy, Ho, Er, Tm, Lu, and Sc) and some mixed metal counterparts]]>

Marilyn M. Olmstead; Tianming Zuo; Harry C. Dorn; Tinghui Li; Alan L. Balch

首页> 外文期刊>Inorganica Chimica Acta >3N@ I h -C 80 (M=Gd, Tb, Dy, Ho, Er, Tm, Lu, and Sc) and some mixed metal counterparts]]>

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3N@ I h -C 80 (M=Gd, Tb, Dy, Ho, Er, Tm, Lu, and Sc) and some mixed metal counterparts]]>

机译：<！[CDATA [金属离子尺寸和富勒烯氮化物单元的金属离子单元：M 3 N @ i h -c 80 （m = gd，tb ，dy，ho，er，tm，lu和sc）和一些混合金属对应物]]>

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?Structures of Er3N@Ih-C80and Ho3N@Ih-C80were determined by single crystal X-ray diffraction.

?For M3N@Ih-C80the thermal ellipsoids of the nitrogen elongate as the size of the metal ion increases.

?The M3N unit becomes pyramidalized when the sum of the crystal radii of the metal ions exceeds 3.05?.

Abstract

The structures of Er

机译：<！[cdata [

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< CE：简单段ID =“SP0010”View =“全部”>

？ er 3 n @ i H -C 80 和HO 3 N @ I H -C 8 0 由单晶X射线衍射确定。

？< / ce：标签> 为m 3 n @ i H -C 80 氮气的热椭圆形作为尺寸金属离子增加。

？ M 3 N单元当金属离子的晶体半径超过3.05时变为金字塔。

抽象

er的结构

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来源
《Inorganica Chimica Acta》 |2017年第2017期|共6页
作者
Marilyn M. Olmstead; Tianming Zuo; Harry C. Dorn; Tinghui Li; Alan L. Balch;
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Department of Chemistry University of California;

Department of Chemistry Virginia Polytechnic Institute and State University;

Department of Chemistry Virginia Polytechnic Institute and State University;

Department of Chemistry Virginia Polytechnic Institute and State University;

Department of Chemistry University of California;

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中图分类无机化学;
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机译：<！[CDATA [金属离子尺寸和富勒烯氮化物单元的金属离子单元：M 3 N @ i h -c 80 （m = gd，tb ，dy，ho，er，tm，lu和sc）和一些混合金属对应物]]>
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3N@ I h -C 80 (M=Gd, Tb, Dy, Ho, Er, Tm, Lu, and Sc) and some mixed metal counterparts]]>

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