Photocatalytic CO<sub>2</sub> Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO<sub>2</sub>, CO, or Proton

Tomoe Shimoda; Takeshi Morishima; Koichi Kodama; Takuji Hirose; Dmitry E. Polyansky; Gerald F. Manbeck; James T. Muckerman; Etsuko Fujita

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Photocatalytic CO₂ Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO₂, CO, or Proton

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Photocatalytic CO₂ Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO₂, CO, or Proton

机译：通过Trigonal-BizyraInaL钴（II）聚吡啶基复合物的光催化CO _{2 减少：钴（I）和钴（0）复合物在其与CO _{2 ，CO的反应上的性质，或质子}}

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机译：<！[cdata [cobalt络合物co〜（ii）l1（pf_（6））_（2）（ 1; l1 = 2,6- bis [2-（2,2'-bipyridin-6' - 乙基]吡啶）和CO〜（II）L2（PF_（6））_（2）（ 2; L2 = 2,6-双[2-（4-甲氧基-2,2'-合成Biphyridin-6'-Y1）乙基]吡啶并用于冷催化CO_（2）还原乙腈。复合物 1和 2的X射线结构揭示了与CO（II）中心配位的配体的所有氮原子的扭曲的分流 - 双滤网几何形状，与常见的六坐标钴络合物与与起相萘吡啶相比单齿溶剂完成协调球的配体。在电化学条件下，在CO（I / 0）氧化还原耦合附近的催化电流在CO（I / 0）氧化还原耦合附近，用于在 n = 1和0）。单电子还原的复合物 2与CO产生[CO〜（0）L2（CO）]与ν_（CO）= 1894cm〜（-1）与[CO〜（II）L2一起产生[CO〜（0）L2（CO）] 〜（2+）通过乙腈中的歧化反应，基于光谱和电化学数据。电化学和时间分辨的UV-VIS光谱表明，具有慢的CO结合速率与[CO〜（I）L2]〜（+）物种，与COL1复合物的密度泛函理论计算一致，其预测来自三角形的大结构变化扭曲的四边形g的双滤网 展开▼

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2018年第9期|共13页

作者
Tomoe Shimoda; Takeshi Morishima; Koichi Kodama; Takuji Hirose; Dmitry E. Polyansky; Gerald F. Manbeck; James T. Muckerman; Etsuko Fujita;
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Chemistry Division Brookhaven National Laboratory Upton New York 11973-5000 United States;

Graduate School of Science and Engineering Saitama University Saitama 338-8570 Japan;

Graduate School of Science and Engineering Saitama University Saitama 338-8570 Japan;

Graduate School of Science and Engineering Saitama University Saitama 338-8570 Japan;

Chemistry Division Brookhaven National Laboratory Upton New York 11973-5000 United States;

Chemistry Division Brookhaven National Laboratory Upton New York 11973-5000 United States;

Chemistry Division Brookhaven National Laboratory Upton New York 11973-5000 United States;

Chemistry Division Brookhaven National Laboratory Upton New York 11973-5000 United States;

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1. Photocatalytic CO₂ Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO₂, CO, or Proton [J] . Tomoe Shimoda, Takeshi Morishima, Koichi Kodama, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2018,第9期

机译：通过Trigonal-BizyraInaL钴（II）聚吡啶基复合物的光催化CO _{2 减少：钴（I）和钴（0）复合物在其与CO _{2 ，CO的反应上的性质，或质子}}

2. COMPLEXES WITH NSO AND N2S2 DONOR LIGANDS - COBALT(II), COBALT(III) AND NICKEL(II) COMPLEXES OF 2,4-BIS(2'-MERCAPTOPHENYLIMINO)PENTANE, 2-(2-MERCAPTOPHENYL)IMINO-4-PENTANONE AND 2-(2-MERCAPTOPHENYL)-SALICYLALDININE AND THEIR REACTIONS [J] . Day K., Chakraborty K., Mallick AK., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry . 1995,第9期

机译：具有NSO和N2S2配体配位化合物的配合物-2,4-双（2'-巯基亚苯基亚氨基）戊烷，2-（2-巯基苯基）亚氨基-4-戊酮的钴（II），钴（III）和镍（II）配合物和2-（2-巯基苯基）-水杨醛碱及其反应

3. Synthesis and structure of some cobalt(II), cobalt(III) and one nickel(II) monomeric, monodentate(S) thiosulfato complexes. Trans and cis structural effects in the cobalt(III) complexes. [J] . Alan Carter, Michael G. B. Drew Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第10期

机译：某些钴（II），钴（III）和一种镍（II）单体单齿硫代硫酸根配合物的合成和结构。钴（III）配合物中的反式和顺式结构效应。

4. Cobalt Catalysis in the Gas Phase: Experimental Characterization of Cobalt(I) Complexes as Intermediates in Regioselective Diels-Alder Reactions [C] . Lukas Fiebig, Julian Kuttner, Gerhard Hilt, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2013

机译：气相中的钴催化剂：钴（I）复合物的实验表征作为区域选择性Diels-Alder反应中的中间体

5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。

6. Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions [O] . William R. McNamara, Zhiji Han, Chih-Juo (Madeline) Yin, 2012

机译：钴-二硫烯配合物用于光催化和电催化还原水溶液中的质子

7. Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton [O] . -1

机译：通过Trigonal-BizyraInaL钴（II）聚吡啶络合物的光催化二氧化碳减少：钴（I）和钴（0）复合物在其与CO 2，CO，CO或质子的反应上的性质

1. 氮掺杂石墨烯/四氧化三铁复合物负载含硫氮杂钴卟啉光催化降解有机污染物 [J] . 操兰 ,杨昌军 ,邓克俭 . 化学与生物工程 . 2018,第005期

2. 氧化钴和氮掺杂碳纳米管纳米复合物的催化与容量性质(英文) [J] . Olga Yu.Podyacheva ,Andrei I.Stadnichenko ,Svetlana A.Yashnik . 催化学报 . 2014,第6期

3. 吖啶和钴肟配合物协同光催化苯乙烯放氢二聚反应构筑1,2-二氢-1-芳基萘 [J] . 曹文晓 ,吴成娟 ,雷涛 . 催化学报 . 2018,第007期

4. 铜钴镍铁氧体/聚苯胺复合物的制备及其电磁性能 [J] . 郭肇基 ,王黎明 ,徐旸 . 材料科学与工程学报 . 2021,第006期

5. 沉积电流对水热电沉积法制备硫/钴/镍/氧/复合物超级电容电极材料的影响研究 [J] . 雷灵均 ,柳乔 ,吴端阳 . 广东化工 . 2020,第008期

6. 钴铜镍铁氧体/碳纳米管复合物的制备及电磁性能 [C] . Qiushi Xiao ,肖秋实 ,Bin Hao . 2012年中西部地区无机化学化工学术研讨会 . 2012

7. 钴/硫化钴/碳复合物微生物燃料电池阴极性能的研究 [A] . 李瑞 . 2016

1. 一种吡啶基钴酞菁-钴复合物/石墨烯复合材料及其制备方法 [P] . 中国专利： CN103985885B . 2016.04.06

2. 一种吡啶基钴酞菁-钴复合物/石墨烯复合材料及其制备方法 [P] . 中国专利： CN103985885A . 2014-08-13

3. Amino acid complexes of cobalt (III) mesoporphyrin IX and cobalt (III) protoporphyrin IX [P] . 外国专利： US5929064A . 1999-07-27

机译：钴（III）中卟啉IX和钴（III）原卟啉IX的氨基酸复合物

4. Amino acid complexes of cobalt (III) mesoporphyrin IX and cobalt (III) protoporhyrin IX. [P] . 外国专利： ZA966549B . 1997-02-18

机译：钴（III）中卟啉IX和钴（III）原卟啉IX的氨基酸复合物。

5. AMINO ACID COMPLEXES OF COBALT (III) MESOPORPHYRIN IX AND COBALT (III) PROTOPORPHYRIN IX [P] . 外国专利： WO9705152A1 . 1997-02-13

机译：钴（III）间卟啉IX和钴（III）原卟啉IX的氨基酸复合物

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Photocatalytic CO2 Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO2, CO, or Proton

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Photocatalytic CO₂ Reduction by Trigonal-Bipyramidal Cobalt(II) Polypyridyl Complexes: The Nature of Cobalt(I) and Cobalt(0) Complexes upon Their Reactions with CO₂, CO, or Proton