Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

Yamaguchi Tadashi; Yoshiya Kohei

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

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Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

机译：三核PT2HG复合体的配位异构体，其金属金属键类型不同

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New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) angstrom, and the other is the Pt -> Hg -> Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) angstrom, and one metal-metal dative bond, Pt -> Hg = 2.6635(7) angstrom.

机译：孤立金属金属键类型不同的新型异构体。一种是pt-hg-pt复合物，具有两个金属 - 金属共价键，pt-hg = 2.5459（8）和2.5483（7）埃，而另一个是pt - > hg - > pt复合物，具有一种金属金属共价键，Pt-Hg = 2.5744（6）埃肚子和一种金属 - 金属Diat键，Pt - > Hg = 2.6635（7）埃。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics 》 |2019年第15期| 共5页
作者
Yamaguchi Tadashi; Yoshiya Kohei;
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作者单位

Waseda Univ Sch Adv Sci &

Engn Dept Chem &

Biochem Tokyo 1698555 Japan;

Waseda Univ Sch Adv Sci &

Engn Dept Chem &

Biochem Tokyo 1698555 Japan;

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正文语种 eng
中图分类化学 ;
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1. Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond [J] . Yamaguchi Tadashi, Yoshiya Kohei Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019 ,第15期

机译：三核PT2HG复合体的配位异构体，其金属金属键类型不同
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Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

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