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Explicitly correlated variational estimates of the energy levels of negative hydrogen ion under spatial confinement

机译：空间限制下的阴性氢离子能量水平的明确相关分析估计

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Abstract > Comprehensive investigations on the structural modifications of negative hydrogen ion within an impenetrable spherical domain has been performed in the framework of Ritz variational method. Electron correlation plays a major role in the formation of H – ion. The Hylleraas‐type basis set expansion of wave function considered here incorporates the effect of electron correlation in an explicit manner. Energy values of <mat:math display="inline" altimg="urn:x-wiley:00207608:media:qua25597:qua25597-math-0001" wiley:location="equation/qua25597-math-0001.png"> <mat:mrow> <mat:msup> <mat:mrow> <mat:mn>1</mat:mn> <mat:mi mathvariant="normal">s</mat:mi> </mat:mrow> <mat:mn>2</mat:mn> </mat:msup> <mat:msup> <mat:mrow> <mat:mo>?</mat:mo> <mat:mo>(</mat:mo> </mat:mrow> <mat:mn>1</mat:mn> </mat:msup> <mat:msup> <mat:mi mathvariant="normal">S</mat:mi> <mat:mi mathvariant="normal">e</mat:mi> </mat:msup> <mat:mo>)</mat:mo> <mat:mo>,</mat:mo> <mat:mo>?</mat:mo> <mat:msup> <mat:mrow> <mat:mn>2</mat:mn> <mat:mi mathvariant="normal">p</mat:mi> </mat:mrow> <mat:mn>2</mat:mn> </mat:msup> <mat:msup> <mat:mrow> <mat:mo>?</mat:mo> <mat:mo>(</mat:mo> </mat:mrow> <mat:mn>3</mat:mn> </mat:msup> <mat:msup> <mat:mi mathvariant="normal">P</mat:mi> <mat:mi mathvariant="normal">e</mat:mi> </mat:msup> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”> <标题类型=“main”>摘要</标题> >在Ritz变分方法的框架中进行了对难以穿球域内的负氢离子的结构修改的综合研究。电子相关在H - </ sup>离子的形成中起主要作用。 Hylleraas型基础设定的波函数的扩展被认为是以明确方式的电子相关性的效果。 <mat：数学显示=“内联”Altimg =“URN：X-Wiley：00207608：媒体：Qua25597：Qua25597-Math-0001”Wiley：Location =“等式/ Qua25597-Math-0001.png”> < MAT：MROW> <MAT：MSUP> <MAT：MROW> <MAT：MN> 1 </ MAT：MN> <MAT：MI MathVariant =“正常”> S </ MAT：MI> </ MAT：MROW> < MAT：MN> 2 </ MAT：Mn> </ MAT：MSUP> <MAT：MSUP> <MAT：MROW> <MAT：MO>？</ MAT：MO> <MAT：MO>（</ MAT：MO > </ MAT：MROW> <MAT：MN> 1 </ MAT：MN> </ MAT：MSUP> <MAT：MSUP> <MAT：MI MathVariant =“普通”> S </ MAT：MI> <MAT： MI Mathvariant =“正常”> E </ MAT：MI> </ MAT：MSUP> <MAT：MO>）</ MAT：MO> <MAT：MO>，</ MAT：MO> <MAT：MO>？ </ mat：mo> <mat：msup> <mat：mrow> <mat：mn> 2 </ mat：mn> <mat：mi mathva RIANT =“正常”> P </ MAT：MI> </ MAT：MROW> <MAT：MN> 2 </ MAT：MN> </ MAT：MSUP> <MAT：MSUP> <MAT：MROW> <MAD：莫>？</ mat：mo> <mat：mo>（</ mo：mo> </ mat：mrow> <mat：mn> 3 </ mat：mn> </ mat：msup> <may：msup> <垫：MI = mathvariant “正常”> P </垫：MI> <垫：MI = mathvariant “正常”>电子</垫：MI> </垫：MSUP> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-21753/'>《International Journal of Quantum Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第14期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chandra Reet&option=202" target="_blank" rel="nofollow">Chandra Reet;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dutta Bibhas&option=202" target="_blank" rel="nofollow">Dutta Bibhas;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saha Jayanta K.&option=202" target="_blank" rel="nofollow">Saha Jayanta K.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bhattacharyya Sukhamoy&option=202" target="_blank" rel="nofollow">Bhattacharyya Sukhamoy;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mukherjee Tapan K.&option=202" target="_blank" rel="nofollow">Mukherjee Tapan K.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of PhysicsNarula Institute of TechnologyAgarpara Kolkata 700 109 India;</p> <p>Department of PhysicsSambhu Nath CollegeLabpur Birbhum 731 303 India;</p> <p>Department of PhysicsAliah UniversityNewtown Kolkata 700 156 India;</p> <p>Department of PhysicsAcharya Prafulla Chandra CollegeNew Barrackpore Kolkata 700 131 India;</p> <p>Department of PhysicsNarula Institute of TechnologyAgarpara Kolkata 700 109 India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=confinement&option=203" rel="nofollow">confinement;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electron correlation&option=203" rel="nofollow">electron correlation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=negative hydrogen ion&option=203" rel="nofollow">negative hydrogen ion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=variational method&option=203" rel="nofollow">variational method;</a> </p> <div class="translation"> 机译：限制;电子相关;负氢离子;变分法; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019755830.html">Explicitly correlated variational estimates of the energy levels of negative hydrogen ion under 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