Dilithium Tetrachloromanganate an Effective Reagent for Regioselective Ring Opening of Epoxides with Grignard Reagents

Santosh S. Devkate; Arvind S. Burungale; Ashok S. Pise

首页> 外文期刊>Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry >Dilithium Tetrachloromanganate an Effective Reagent for Regioselective Ring Opening of Epoxides with Grignard Reagents

【24h】

Dilithium Tetrachloromanganate an Effective Reagent for Regioselective Ring Opening of Epoxides with Grignard Reagents

机译：四氯铝酸盐与GRIGNARD REAGENTS的EPOXINES的有效试剂

获取原文

获取原文并翻译 | 示例

获取外文期刊封面目录资料

开具论文收录证明 >>

文献代查 >>

文献数据库（团队版） >>

页面导航

摘要
著录项
引文网络
相似文献
相关主题

摘要

The epoxides were obtained from substituted phenols and epicMorohydrin by reported methods. The regioselective ring opening of epoxides were studied in different solvents by reaction with Grignard's reagent in presence of dilithium tetrachloromanganate.

机译：通过报道的方法从取代的酚和异摩尔醇获得环氧化物。通过与格氏试剂在四氯锰酸碳酸铝存在下反应，在不同溶剂中研究了环氧化物的区域选择性环。

著录项

来源
《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2019年第12期|共5页
作者
Santosh S. Devkate; Arvind S. Burungale; Ashok S. Pise;
展开▼
作者单位

Deparartment of Chemistry Rayat Sikshan Sanstha's S.M. Joshi College Hadapsar Pune-411028 India;

Deparartment of Chemistry Rayat Sikshan Sanstha's S.M. Joshi College Hadapsar Pune-411028 India;

Deparartment of Chemistry Rayat Sikshan Sanstha's S.M. Joshi College Hadapsar Pune-411028 India;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Epoxide; Epichlorohydrin; Regioselective; Grignard; Transmetallation.;

机译：环氧化物;表氯醇;区域选择性;格氏;传输组合。;

相似文献

外文文献
中文文献
专利

1. Reaction of Polymer-supported Selenovinyl Bromide with Grignard Reagents: A Facile Route to the Synthesis of(E)-1, 2-Disubstituted Olefins [J] . E TANG, Xiang Jin LIN, Lu Ling WU 中国化学快报（英文版） . 2005,第008期
2. Synthesis of Large-ring Cycloalkanediones from Bis-Grignard Reagent and Dinitriles [J] . Bing Qin YANG, Ju Li JIANG, Yin Juan BAI, 中国化学快报（英文版） . 2004,第001期
3. (Z)-α-Selanyl Alkenyl Grignard Reagents as Convenient Precursors for Stereoselective Synthesis of Trisubstituted Alkenes [J] . 中国化学快报（英文版） . 2002,第012期
4. Studies on New Additions to 5-Methoxy-2 (5H)-Furanone: 1, 4-Addition of Grignard Reagents, and 1,3-Dipolar Cycloaddition of Silyl Nitronates [J] . 中国化学快报（英文版） . 2001,第004期
5. Dilithium Tetrachloromanganate an Effective Reagent for Regioselective Ring Opening of Epoxides with Grignard Reagents [J] . Santosh S. Devkate, Arvind S. Burungale, Ashok S. Pise Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2019,第12期

机译：四氯铝酸盐与GRIGNARD REAGENTS的EPOXINES的有效试剂
6. Regioselectivity in the addition of grignard reagents to bis(2-benzothiazolyl) ketone: C- vs. O-alkylation using aryl grignard reagents [J] . Boga C., Micheletti G. European journal of organic chemistry . 2010,第29期

机译：在双（2-苯并噻唑基）酮中添加格氏试剂的区域选择性：使用芳基格氏试剂的C-对O-烷基化
7. Development of a Robust Procedure for the Copper-catalyzed Ring-Opening of Epoxides with Grignard Reagents [J] . Mahbub Alam, Christopher Wise, Carl A. Baxter Organic process research & development . 2012,第3期

机译：格氏试剂对铜催化环氧化物开环的稳健方法的开发
8. Ni-Catalyzed Regioselective Three-Component Coupling Reaction of Terminal Alkynes, Alkyl Halides, and Grignard Reagents [C] . Fumiaki Bando, Jun Terao, Nobuaki Kambe Symposium on Organometallic Chemistry . 2008

机译：Ni催化末端炔烃，烷基卤化物和格氏试剂的三组分偶联反应
9. A reiterative approach for the synthesis of the C(28)-C(20) fragment of rifamycin S polypropionate chain by the diastereoselective preparation and regioselective cleavage of oxiranes. Efficient and regioselective copper catalyzed alkenyl Grignard cleavage of 1,2-disubstituted epoxides [D] . Rodriguez Reyes, David 2006

机译：一种通过非对映选择性制备和区域选择性裂解环氧乙烷来合成利福霉素S聚丙烯酸酯链的C（28）-C（20）片段的迭代方法。高效和区域选择性铜催化的1,2-二取代环氧化物烯基格利雅裂解
10. Regioselective addition of Grignard reagents to N-acylpyrazinium salts: synthesis of substituted 12-dihydropyrazines and Δ5-2-oxopiperazines [O] . Valentine R St. Hilaire, William E Hopkins, Yenteeo S Miller, 2019

机译：格氏试剂向N-酰基吡嗪鎓盐的区域选择性加成：取代的12-二氢吡嗪和Δ5-2-氧哌嗪的合成
11. Task specific ionic liquid as solvent, catalyst and reagent for regioselective ring opening of epoxides in water [O] . Rezaee Nezhad Eshagh, Sajjadifar Sami, Heidarizadeh Fariba, 2015

机译：特定任务的离子液体作为溶剂，催化剂和试剂，用于水中环氧的区域选择性开环

Dilithium Tetrachloromanganate an Effective Reagent for Regioselective Ring Opening of Epoxides with Grignard Reagents

摘要

著录项

引文网络

相似文献

相关主题

期刊订阅