Resolution and determination of the absolute configuration 2,2′-diacetyl-3,3′, 4,4′-tetramethyl-1,1′- diphosphaferrocenes

K?ys A.

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Resolution and determination of the absolute configuration 2,2′-diacetyl-3,3′, 4,4′-tetramethyl-1,1′- diphosphaferrocenes

机译：解析和确定2,2'-二乙酰-3,3'，4,4'-四甲基-1,1'-二磷二茂铁的绝对构型

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(±)-2,2′-diacetylyl-3,3′, 4,4′-tetramethyl-1, 1′diphosphaferrocene (1) was resolved via semi preparative HPLC. The absolute configuration (-)-1 has been determined by X-ray crystallography. The circular dichroism spectra of the (1) are also reported and discussed.

机译：通过半制备HPLC拆分（±）-2，2′-二乙酰基-3，3′，4，4′-四甲基-1，1′二磷二茂铁（1）。绝对构型（-）-1已经通过X射线晶体学确定。还报道和讨论了（1）的圆二色性光谱。

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《Journal of Organometallic Chemistry》 |2012年第null期|共3页
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K?ys A.;
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正文语种 eng
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Chiral separation; Circural dichroism of metallocenes; Diphosphaferrocene; Planar chiral;

机译：手性分离茂金属的圆二色性二磷二茂铁平面手性;

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1. Resolution and determination of the absolute configuration 2,2′-diacetyl-3,3′, 4,4′-tetramethyl-1,1′- diphosphaferrocenes [J] . K?ys A. Journal of Organometallic Chemistry . 2012,第Null期

机译：解析和确定2,2'-二乙酰-3,3'，4,4'-四甲基-1,1'-二磷二茂铁的绝对构型
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机译：立体异构体2,2'-二苯甲酰基-3,3'，4,4'-四甲基-1,1'-二磷杂二茂铁的合成及结构测定

Resolution and determination of the absolute configuration 2,2′-diacetyl-3,3′, 4,4′-tetramethyl-1,1′- diphosphaferrocenes

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