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Structural phase transitions in EuFe_2As_2 superconductor at low temperatures and high pressures

机译:EuFe_2As_2超导体在低温和高压下的结构相变

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The crystal structure of EuFe_2As_2 has been studied up to a pressure of 35GPa and down to a temperature of 8K using temperature dependent x-ray diffraction in a diamond anvil cell at a synchrotron source. At 4.3GPa, we have detected a structural phase transition from a high temperature tetragonal phase with I4/mmm space group to a low temperature orthorhombic phase with Fmmm space group around 120K. With the application of pressure at a low temperature of 10K, the orthorhombic phase is suppressed and a phase change to a collapsed tetragonal phase with I4/mmm space group is observed at 11GPa. This collapsed tetragonal phase is similar to the one observed at ambient temperature and pressure above 8.5GPa. We have shown that the collapsed tetragonal phase of EuFe_2As_2 has the same pressurevolume (PV) equation of state at ambient temperature and at 10K, implying that the high pressure phase of EuFe_2As_2 has a negligible thermal expansion coefficient.
机译:在温度为35GPa的压力下,在温度为8K的温度下,通过在同步加速器源的金刚石砧座中使用温度相关的X射线衍射研究了EuFe_2As_2的晶体结构。在4.3GPa时,我们已经检测到结构相从I4 / mmm空间群的高温四方相转变为Fmmm空间群在120K左右的低温正交相。通过在10K的低温下施加压力,可以抑制正交相,并且在11GPa时观察到相转变为I4 / mmm空间基团的塌方四方相。这种塌陷的四方相类似于在环境温度和高于8.5GPa的压力下观察到的相。我们已经表明,在环境温度和10K下,EuFe_2As_2的塌方四方相具有相同的压力体积(PV)状态方程,这表明EuFe_2As_2的高压相具有可忽略不计的热膨胀系数。

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