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首页> 外文期刊>Journal of Physics. Condensed Matter >Defect-induced defect-mediated magnetism in ZnO and carbon-based materials
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Defect-induced defect-mediated magnetism in ZnO and carbon-based materials

机译:ZnO和碳基材料中的缺陷诱导的缺陷介导的磁性

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摘要

The recent discovery of magnetism in a variety of diverse non-magnetic materials containing defects has challenged conventional thinking about the microscopic origin of magnetism in general. Especially intriguing is the complete absence of d electrons that are traditionally associated with magnetism. By a systematic microscopic investigation of two completely dissimilar materials (namely, ZnO and rhombohedral-C_(60) polymers) exhibiting ferromagnetism in the presence of defects, we show that this new phenomenon has a common origin and the mechanism responsible can be used as a powerful tool for inducing and tailoring magnetic features in systems which are not magnetic otherwise. Based on our findings, we propose a general recipe for developing ferromagnetism in new materials of great technological interest. The recipe is quite general, although its realization is system specific. In each case, the required basic step is to find two synergistic codopants, one for providing the unpaired electrons and the other for facilitating the ferromagnetic coupling.
机译:在包含缺陷的多种多样的非磁性材料中,磁性的最新发现挑战了通常关于磁性微观起源的传统思维。特别令人着迷的是,完全没有传统上与磁性有关的d电子。通过对存在缺陷的两种表现出铁磁性的完全不同的材料(即ZnO和菱面体C_(60)聚合物)进行系统的显微镜研究,我们证明了这种新现象具有共同的起源,并且其机理可以用作用于在非磁性系统中感应和调整磁性特征的强大工具。根据我们的发现,我们提出了在具有重大技术意义的新材料中开发铁磁性的一般方法。该配方相当通用,尽管其实现是系统特定的。在每种情况下,所需的基本步骤是找到两种协同共掺杂剂,一种用于提供不成对的电子,另一种用于促进铁磁耦合。

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