Prediction of the critical reduced electric field strength for carbon dioxide and its mixtures with 50% O_2 and 50% H_2 from Boltzmann analysis for gas temperatures up to 3500K at atmospheric pressure

摘要

This paper provides theoretical calculations that predict the dielectric breakdown properties of carbon dioxide (CO_2) and its mixtures with 50% O_2 and 50% H_2 for a gas temperature range of 300-3500K at 0.1MPa. CO_2 is one of the most likely candidates for an environment-friendly arc-quenching medium to replace SF_6 in high-voltage circuit breakers. Initially, the electron energy distribution function (EEDF) is derived by solving the Boltzmann equation under the zero-dimensional two-term spherical harmonic approximation. Then the reduced ionization and attachment coefficients are obtained, based on the calculated EEDF. Finally, the critical reduced electric field strength (E/N)_(cr), which is defined as the value for which total ionization reactions are equal to total attachment reactions, is obtained and analysed. The results demonstrate the superior breakdown properties of a 50% CO_2-50% O_2 mixture to those of both pure CO_2 and 50% CO_2-50% H_2. Nearly no deviation in (E/N)_(cr) is found in a 50% CO_2-50% O_2 mixture for gas temperatures up to 2500 K, and although there is clear reduction as the gas temperature is increased further to 3500 K, the value remains higher than that of pure CO_2.